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A Study on the Thermal Treatment Possibility of Chlorinated Flame Retardants(CFRs) Containing Wastes
- 언어ENG
- URLhttps://db.koreascholar.com/Article/Detail/343135
Elemental analysis, calorific value, etc. were measured to obtain basic information such as decomposition temperature and required oxygen amount for thermal treatment of waste containing chlorine-based flame retardant. Moisture, flammability and ash content of polyurethane foam were high in water, flammable rubber sheet in case of ash and flame retardant rubber sheet in case of ash. As a result of thermogravimetric analysis, the weight change in the range of 300 ~ 600 ℃ was large. The content of chlorinated flame retardant agent was analyzed to be higher than that of polyurethane foam (4,253.09 mg/kg), cell phone case (cloth, leather) 628.29 mg/kg and flame retardant rubber sheet 341.91 mg/kg. Chlorinated flame retardant materials, TDCP and TDCPP, were not detected in all samples. As a result of the decomposition tests for chlorine-based flame retardants at 850 ℃ and 1,100 ℃, chlorine-based flame retardant components were not detected in exhaust gas at all at 1,100 ℃ as well as at 850 ℃ in all samples including mobile phone cases, flame retardant rubber sheets and car seats. As a result of calculating the conversion rate for total chlorine value, it showed more than 99% even at 850 ℃ as well as at 1,100 ℃. Considering the decomposition rate in laboratory experiments of chlorine-based flame retardant-containing wastes, it is considered possible to incinerate at a scale of 2 ton/hour or more, which is the existing incineration facility. It is judged that it is not necessary to set separate operating conditions or preventive facility standards since the material is decomposed sufficiently at 850 ℃ or more. However, considering the possibility of dioxin or unintentional persistent organic pollutants, it is considered appropriate to operate at above 1,100 ℃.
