Thermally rearranged polybenzoxazole (TR-PBO) membranes has a excellent gas separation properties due to its high fractional free volume and suitable cavity size.1) Furthermore, thermally rearranged poly(benzoxazole-co-imide) (TR-PBOI) materials show the improved mechanical strength and gas separation properties.2) In this study, TR-PBOI asymmetric hollow fiber membranes was fabricated via NIPS method. In detail, the influence of co-solvent system and polymeric additives with various molecular weight on gas separation performance was observed. For further performance optimization, dope & bore flow rate and coagulation temperature were controlled.3) The characterization on membranes was conducted by FE-SEM, pure and mixed gas permeation test with micro-GC system.

• 김주성(한양대학교 에너지공학과, Department of Energy Engineering, College of Engineering, Hanyang University) | Ju Sung Kim
• 우경택(한양대학교 에너지공학과, Department of Energy Engineering, College of Engineering, Hanyang University) | Kyung Teak Woo
• 이종명(한양대학교 에너지공학과, Department of Energy Engineering, College of Engineering, Hanyang University) | Jongmyeong Lee
• Guangxi Dong(한양대학교 에너지공학과, Department of Energy Engineering, College of Engineering, Hanyang University)
• 도유성(한양대학교 에너지공학과, Department of Energy Engineering, College of Engineering, Hanyang University) | Yu Seong Do
• 이영무(한양대학교 에너지공학과, Department of Energy Engineering, College of Engineering, Hanyang University) | Young Moo Lee