The gas separation through membrane is considered as a promising solution for the stabilization of greenhouse gas level of atmosphere attributed from CO2. The separation process of membrane allows low energy requirement, low cost, and ease of operation. However, conventional polymeric membranes generally suffer from the trade-off between permeability and selectivity, which remains as one of the most important challenges for commercialization. Mixed matrix membranes (MMMs), consisting of a polymer matrix and porous nano-filler, are considered to be a promising solution to overcome the trade-offs in polymeric membranes. Herein the porous nano-structures were fabricated to enhance the permselectity of CO2 separation membranes. The MMM which were fabricated with prepared porous nano-filler showed permeability improvement without significant selectivity loss.