Since the first development of asphalt emulsion in 1920, the asphalt emulsions have been in existence for almost 100 years. The advantages of asphalt emulsion compared to hot asphalt and cut back binders are related to the low application temperature, compatibility with other water-based binders like rubber latex and cement, and lowsolvent content. Surface active agents(surfactants), also known as emulsifiers or emulsifying agents, are needed to provide the stability required over time. The type of asphalt emulsion is largely divided into two for the mixture which acts as a binder by mixing with the aggregate and for the bonding strength between asphalt pavement layers. The cold recycled asphalt mixture is affected the binding strength between asphalt and aggregate, depending on the properties of the asphalt binder as well as the emulsifier properties. Four kinds of emulsifiers(alkyl amines, ligine amine, fatty amine, alkyl amido polyamines) were used to make emulsified asphalt, and their basic properties (storage stability, cement mixing test, penetration, etc.) and aggregate film separation were measured. As a result, the penetration of the asphalt emulsion made by the type of alkyl amido polyamines emulsifier was measured to be about 10.4% higher, and the stripping of the bitumen-aggregate film was also lower about 21%. This is because polyamine has two or more primary amino groups –NH2 forms a strong binding force.