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용제를 사용하지 않는 친환경 폴리우레탄 접착제의 합성 및 물성 : DPE-41, TDI, 개시제 및 가소제량의 영향 KCI 등재

Synthesis and Properties of Eco-friendly Polyurethane Adhesive without Solvent : Effect of DPE-41, TDI, Initiator and Plasticizer Content

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

In this experiment no solvent based polyurethane(PU) adhesives were prepared with the polyol, isocyanate, dioctyl phthalate(DOP), 2-hydroxyethylacrylate(2-HEA) and other acrylate monomers. The softenening point of the PU adhesives measured by Ring & Ball method were examined in the present study. And adhesion strength and mechanical properties such as tensile strength and 100% modulus of the PU adhesives were evaluated by Universal Test Machine. The experimental results showed that increase of both DPE-41, benzoylperoxide(BPO) and toluene diisocyanate(TDI) increased softenening point, adhesion strength, tensile strength and 100% modulus. However as DOP content increased sofenening point, adhesion strength decreased and tensile strength, 100% modulus also decreased.

목차
Abstract
 1. 서 론
 2. 재료 및 실험방법
  2.1. 무용제형 polyurethane 중합반응
  2.2. 특성평가
 3. 결과 및 고찰
  3.1. DPE-41의 함량변화에 따른 영향
  3.2. TDI 함량변화에 따른 영향
  3.3. 개시제 함량변화에 따른 영향
  3.4. 가소제 함량변화에 따른 영향
 4. 결론
 감사의 글
 참고문헌
저자
  • 류기정(부경대학교 공과대학 고분자공학과) | Ki-Jung Ryu (Dept. of Polymer Engineering, Pukyong National University)
  • 박찬영(부경대학교 공과대학 고분자공학과) | Chan-Young Park (Dept. of Polymer Engineering, Pukyong National University) Corresponding author