논문 상세보기

촉매성 산화물 전극을 이용한 페놀의 전기화학적 분해 KCI 등재

Electrochemical Degradation of Phenol Using Dimensionally Stable Anode

  • 언어KOR
  • URLhttps://db.koreascholar.com/Article/Detail/358587
서비스가 종료되어 열람이 제한될 수 있습니다.
한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

Electrochemical degradation of phenol was evaluated at DSA (dimensionally stable anode), JP202 (Ru, 25%; Ir, 25%; other, 50%) electrode for being a treatment method in non-biodegradable organic compounds such as phenol. Experiments were conducted to examine the effects of applied current (1.0~4.0 A), electrolyte type (NaCl, KCl, Na2SO4, H2SO4) and concentration (0.5~3.0 g/L), initial phenol concentration (12.5~100.0 mg/L) on phenol degradation and UV254 absorbance as indirect indicator of by-product degraded phenol. It was found that phenol concentration decreased from around 50 mg/L to zero after 10 min of electrolysis with 2.5 g/L NaCl as supporting electrolyte at the current of 3.5 A. Although phenol could be completely electrochemical degraded by JP202 anode, the degradation of phenol COD was required oxidation time over 60 min due to the generation of by-products. UV254 absorbance can see the impact of as an indirect indicator of the creation and destruction of by-product. The initial removal rate of phenol is 5.63 times faster than the initial COD removal rate.

목차
Abstract
 1. 서 론
 2. 재료 및 방법
  2.1. 실험재료
  2.2. 분석 및 측정
 3. 결과 및 고찰
  3.1. 페놀 분해와 UV254 변화에 미치는 전류의 영향
  3.2. 페놀 분해와 UV254 흡광도에 미치는 전해질 종류의영향
  3.3. 페놀 분해와 UV254 흡광도에 미치는 전해질 농도의영향
  3.4. 페놀 분해와 UV254 흡광도에 미치는 초기 페놀 농도의영향
 4. 결 론
 참 고 문 헌
저자
  • 김동석(대구가톨릭대학교 환경과학과) | Dong-Seog Kim (Department of Environmental Science, Catholic University of Daegu)
  • 박영식(대구대학교 기초교육원) | Young-Seek Park (Faculty of Liberal Education, Daegu University) Corresponding author