논문 상세보기
pp.687-700
new N3-O2 pentadentate ligand, H-BHPT, was synthesized. Hydrochloric acid salts of Br-BHPT, Cl-BHPT, CH3O-BHPT and CH3-BHPT, having Br-, Cl-, CH3- and CH3O- substituents at the para position of the phenol hydroxyl group of H-BHPT were synthesized. Hydrochloric acid salts of 3OH-BHPT and 4OH-BHPT, having different position of the phenol hydroxyl group of H-BHPT were also synthesized. The synthesis of each ligand was confirmed by C. H. N. atomic analysis and 1H NMR, 13C NMR, UV-visible, and mass spectra. The calculated proton dissociation constants (logKn H) of the phenol hydroxyl group and secondary amine group of the synthesized N3-O2 ligands showed five steps of the proton dissociations. The order of the overall proton dissociation constants (logβp) of the ligands was Br-BHPT < Cl-BHPT < H-BHPT < CH3O-BHPT < CH3-BHPT. The order agreed with that of Hammett substituent constants (δp). However, dissociation steps of 3OH-BHPT were four and that of 4OH-BHPT was three. The calculated stability constants (logKML) between the ligands and transition metal ions agreed with the order of logβp values of the ligands. The order of the stability constants between the transition metal ions with the synthesized ligands was Co(Ⅱ) < Ni(Ⅱ) < Cu(Ⅱ) > Zn(Ⅱ) > Cd(Ⅱ) > Pb(Ⅱ). The order agreed well with that of the Iriving-Williams.
1. 서 론
2. 재료 및 방법
2.1. 시약 및 기기
2.2. 다섯 자리 질소-산소 계 리간드 BHPT의 합성
2.3. 리간드의 양성자 단계해리상수 결정
2.4. 중금속(Ⅱ) 이온과의 안정도 상수 결정
3. 결과 및 고찰
3.1. 다섯 자리 질소-산소 계 리간드 BHPT의 합성
3.2. 리간드의 양성자 단계해리상수 값 결정
3.3. 중금속(Ⅱ) 이온과의 착물 안정도상수 값 결정
4. 결 론
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