The objectives of this study were conducted to determine the effects of two chemical amendments on volatile fatty acids (VFA) and nitrogen contents in poultry litter after broiler chicks were raised in poultry houses for 6 weeks. Two different additives were applied as a top dressing to the litter at a rate of AlCl₃∙6₂2O (200 g)+CaCO₃ (50 g) or Alum (200 g)+CaCO₃ (50 g)/kg of rice bran; untreated litter served as controls. Application of AlCl₃+CaCO₃ and Alum+CaCO₃ reduced total VFA contents by 67% and 51% at 6 weeks, respectively, compard to the control groups. The decrease in litter pH with two chemical treatments results in decreased proportion of VFA and increased nitrogen contents of the litter. These results indicate that treating AlCl₃+CaCO₃ and Alum+CaCO₃ to poultry litter offers the potential for reducing an environmental impact.