Morphological Change and Luminescence Properties of ZnO Crystals Synthesized by Thermal Evaporation of a Mixture of Zn and Cu Powder
ZnO crystals with different morphologies are synthesized through thermal evaporation of the mixture of Zn and Cu powder in air at atmospheric pressure. ZnO crystals with wire shape are synthesized when the process is performed at 1,000 oC, while tetrapod-shaped ZnO crystals begin to form at 1,100 oC. The wire-shaped ZnO crystals form even at 1,000 oC, indicating that Cu acts as a reducing agent. As the temperature increases to 1,200 oC, a large quantity of tetrapod-shaped ZnO crystals form and their size also increases. In addition to the tetrapods, rod-shaped ZnO crystals are observed. The atomic ratio of Zn and O in the ZnO crystals is approximately 1:1 with an increasing process temperature from 1,000 oC to 1,200 oC. For the ZnO crystals synthesized at 1,000 oC, no luminescence spectrum is observed. A weak visible luminescence is detected for the ZnO crystals prepared at 1,100 oC. Ultraviolet and visible luminescence peaks with strong intensities are observed in the luminescence spectrum of the ZnO crystals formed at 1,200 oC.