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이온교환법에 의한 탈질소 공정개발의 기초연구 ( II ) KCI 등재

Basic Study for Development of Denitrogenation Process by Ion Exchange ( II )

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

Ion exchange performance to remove nitrate in water was studied using commercially available strong base anion exchange resin of Cl^- type in the batch and continuous column reactors. The performance was tested using the effluent concentration histories for continuous column or equilibrium concentrations for batch reactor as a function of time until resins were exhausted or reached ionic equilibrium between resin and solution. Anion exchange resin used in this study was more effective than activated carbon or zeolite for nitrate removal. With large resin amount or low initial concentration, nitrate removal characteristics for a typical gel-type resin was increased. On considering the relation between the breakthrough capacity and nitrate concentration of the influent, the use of anion exchange resin were suitable for the higher order water treatment. The nitrate removal of above 90% could be possible until the effluent of above 650 BV was passed to the column. Thus, the commercially available strong base anion exchange resin of Cl^- type used in this study could be effectively used as economic material for treatment of the groundwater. The breakthrough curves showed the sequence of resin selectivity as SO_4^2- > NO_3, > NO^2- > HCO_3^-. The results of this study could be scaled up and used as a design tool for the water purification system of the real groundwater and surface water treatment processes.

저자
  • 이민규(부경대학교 화학공학과) | Min-Gyu Lee (Dept. of Chemical Engineering, Pukyong University)
  • 주창식(부경대학교 화학공학과) | Chang-Sik Ju (Dept. of Chemical Engineering, Pukyong University)
  • 윤태경(동의대학교 화학공학과) | Tae-Kyung Yoon (Dept. of Chemical Engineering, Dongeui University)
  • 채용곤(동의대학교 화학과) | Yong-Gon Chae (Dept. of Chemistry, Dongeui University)
  • 이동환(동의대학교 화학과) | Dong-Hwan Lee (Dept. of Chemistry, Dongeui University)
  • 오영희(동의대학교 화학과) | Yung-Hee Oh (Dept. of Chemistry, Dongeui University)