The personal exposures of nitrogen dioxide(NO2), microenvironmental levels and daily time activity patterns on Seoul subway station workers were measured from February 10 to March 12, 1999. Personal NO2 exposure for 24 hours were 29.40±9.75 ppb. NO2 level of occupational environment were 27.87±7.15 ppb in office, 33.60±8.64 ppb in platform and 50.13±13.04 ppb in outdoor. Personal exposure time of subway station workers was constituted as survey results with 7.94±3.00 hours in office, 2.82±1.63 hours in platform and 1 hours in outdoor. With above results, personal NO2 exposure distributions on subway station workers in Seoul were estimated with Monte Carlo simulation which uses statistical probabilistic theory on various exposure scenario testing. Some of distributions which did not have any formal patterns were assumed as custom distribution type. Estimated personal occupational NO2 exposure using time weighted average (TWA) model was 31.29±5.57 ppb, which were under Annual Ambient Standard (50 ppb) of Korea. Though arithmetic means of measured personal NO2 exposure was lower than that of occupational NO2 exposure estimated by TWA model, considering probability distribution type simulated, probability distribution of measured personal NO2 exposures for 24 hours was over ambient standard with 3.23%, which was higher than those of occupational exposure (0.02%). Further research is needed for reducing these 24 hour NO2 personal excess exposures besides occupational exposure on subway station workers in Seoul.