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과 액상 형성에 의한 비납계 압전 (Na,K)NbO3−Ba(Cu,Nb)O3 결정립의 비정상 성장 거동 및 전기적 특성 KCI 등재 SCOPUS

Fast Abnormal Grain Growth Behavior and Electric Properties of Lead-Free Piezoelectric (K,Na)NbO3−Ba(Cu,Nb)O3 Grains through Transient Liquid Phase

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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

Pb(Zr,Ti)O3 (PZT) is used for the various piezoelectric devices owing to its high piezoelectric properties. However, lead (Pb), which is contained in PZT, causes various environment contaminations. (K,Na)NbO3 (NKN) is the most well-known candidate for a lead-free composition to replace PZT. A single crystal has excellent piezoelectric-properties and its properties can be changed by changing the orientation direction. It is hard to fabricate a NKN single crystal due to the sodium and potassium. Thus, (Na,K)NbO3-Ba(Cu,Nb)O3 (NKN-BCuN) is chosen to fabricate the single crystal with relative ease. NKNBCuN pellets consist of two parts, yellow single crystals and gray poly-crystals that contain copper. The area that has a large amount of copper particles may melt at low temperature but not the other areas. The liquid phase may be responsible for the abnormal grain growth in NKN-BCuN ceramics. The dielectric constant and tan δ are measured to be 684 and 0.036 at 1 kHz in NKN-BCuN, respectively. The coercive field and remnant polarization are 14 kV/cm and 20 μC/cm2.

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저자
  • 임지호(인하대학교 신소재공학과) | Ji-Ho Lim (Department of Materials Science and Engineering, Inha University)
  • 이주승(인하대학교 신소재공학과) | Ju-Seung Lee (Department of Materials Science and Engineering, Inha University)
  • 이승희(인하대학교 신소재공학과) | SeungHee Lee (Department of Materials Science and Engineering, Inha University)
  • 정한보(인하대학교 신소재공학과) | Han-Bo Jung (Department of Materials Science and Engineering, Inha University)
  • 박춘길(인하대학교 신소재공학과) | Chun-kil Park (Department of Materials Science and Engineering, Inha University)
  • 안철우(한국기계연구원 부설 재료연구소) | Cheol-Woo Ahn (Functional Ceramics Department, Powder & Ceramics Division, Korea Institute of Materials Science (KIMS))
  • 유일열(금오공과대학교 신소재공학과) | Il-Ryeol Yoo (School of Materials Science and Engineering, Kumoh National Institute of Technology)
  • 조경훈(금오공과대학교 신소재공학과) | Kyung-Hoon Cho (School of Materials Science and Engineering, Kumoh National Institute of Technology)
  • 정대용(인하대학교 신소재공학과) | Dae-Yong Jeong (Department of Materials Science and Engineering, Inha University) Corresponding author