논문 상세보기
pp.137-148
Several analytical measurement techniques have been developed over the years for ammonia (NH3). However, the field monitoring of NH3 still remains a significant challenge owing to the wide range of possible environmental conditions and NH3 concentration. In this regard, it is imperative to ensure the quality control of techniques to measure the NH3 emission levels reliably. A present study was conducted to compare the five analytical methods for the measurement of atmospheric NH3 via validation tests under laboratory and field conditions. The analytical instruments applied in the present study were based on wet chemistry, gas detection tube, electrochemical sensor, photoacoustic spectroscopy, and cavity ring-down spectroscopy. The reproducibility and linearity of all the analyzed methods were observed to be high with the relative standard deviation and coefficient of determination (R2) being 10% and > 0.9, respectively. In the case of wet chemistry and high NH3 concentration, the measured NH3 results were found to be close to the actual standard gas levels. Response times of electrochemical sensor showed faster from the instruments utilized more than one year and the high NH3 concentrations. In the field tests, NH3 concentration showed higher in the manure storage tank compared with the pig-pen. In both cases, the NH3 concentration levels measured by gas detection tube were found to be quite different from that of wet chemistry. It was proposed that such differences in NH3 concentration could arise due to the inherent instrumental characteristics and the variations in air velocity during sampling/measurement. The periodic instrumental maintenance, verification, replicate analyses, and suitable consideration of environmental factors should be considered for a more reliable measurement of NH3 concentration under real field conditions.
1. 서 론
2. 연구내용 및 방법
2.1 재현성 및 검량선
2.2 돈방 및 분뇨저장조
2.3 측정방법별 분석기기 사용방법
3. 연구결과 및 고찰
3.1 재현성
3.2 검량선
3.3 돈방 및 분뇨저장조
4. 결 론
References
