One of the harmful substances produced by livestock manure is ammonia (NH3), which is emitted at a high rate. Additionally, NH3 reacts with sulfur oxides (SOx) and nitrogen oxides (NOx) in the atmosphere to produce fine particulate matter (PM2.5). However, the management and countermeasures for NH3 in livestock facilities were found to be inadequate. To establish effective measures, an NH3 emission factor that complies with certified methodologies is required. This study calculates the emission factor by monitoring NH3 concentration and ventilation between September 2022 and May 2023 in a mechanically-ventilated enclosed facility. The data measurement was performed in accordance with the VERA test protocol from Europe, and NH3 concentrations were monitored in real-time using photoacoustic spectroscopy measurement equipment. The average NH3 concentrations for Rooms 1, 2, and 3 during the entire period were measured at 0.96 ± 0.39 ppm, 1.20 ± 0.57 ppm, and 1.34 ± 0.71 ppm, respectively, with an overall average of approximately 1.17 ± 0.49 ppm. The average ventilation was recorded at 2,782.0 ± 1,510.4 m³/h, with an average internal temperature of 26.0 ± 1.5 °C and a relative humidity of 63.9 ± 5.2%. The average emission factor per room was calculated as 0.14 ± 0.03 g/day/pig for Room 1, 0.19 ± 0.07 g/day/pig for Room 2, and 0.15 ± 0.05 g/day/pig for Room 3. Ultimately, this study determined the average NH3 emission factor for the weaned pig facility to be 0.16 g/day/ pig.

Ammonia (NH3) is a basic gas in the atmosphere and is known to play an important role in producing adverse health and environmental effects. Atmospheric NH3 causes stunted livestock growth, decreased visibility, and induces lung diseases when high concentrations occur. In addition, atmospheric NH3 reacts with acidic species (sulfuric acid, nitric acid, etc.) and produces secondary inorganic aerosol. In this study, the NH3 concentration and ventilation of Rooms 1 to 3 inside a sow facility were measured during the period from March 25 to May 31, 2021. It was difficult to conduct long-term field experiments at housing where pigs are raised. However, in order to improve the accuracy and reliability of the data, repeated experiments were conducted in three pig rooms in the same environment. The average concentration of NH3 in Rooms 1 to 3 was measured to be 7.6 ± 2.7 ppm, 8.2 ± 2.8 ppm, and 8.2 ± 2.7 ppm, respectively. The average internal temperatures were 21.0 oC, 21.2 °C, and 21.8 °C, and the internal humidity was 49.3%, 49.2%, and 49.2%, respectively. The ventilation per pig in Rooms 1 to 3 was measured as 60.4m3/hour∙pig, 62.5m3/hour∙pig, and 64.9m3/hour∙pig, respectively. At this time, NH3 emissions from Rooms 1 to 3 were found to be 6.9 ± 0.8 g/day∙pig, 7.9 ± 1.5 g/day∙pig, and 8.2 ± 1.3 g/day∙pig, respectively. As a result of the correlation analysis, the NH3 concentration was analyzed as producing a negative correlation between the ventilation (r=-0.73) and the internal temperature (r=-0.60) increase. Finally, as a result of calculating the national NH3 emission factor, the NH3 emission of one sow room in spring was 7.7 ± 1.4 g/day∙pig, and the NH3 emission of one year was 2.8 kg/ year∙pig.

The sampling bag is used as a storage container for odor gas samples. It is known that the substances recovery rate of odor bags decreases during storage time, and the degree of recovery varies depending on the characteristics of the gas sample and the material of the bag. This study investigated the recovery rate of VFA (ACA, PPA, BTA, VLA) in PEA bags during storage time. In addition, a model was developed to estimate the recovery rate of each substance as a function of time. Standard gas (ACA, PPA, BTA, VLA mixed) recovery rate was used for the model development. The concentration of the compound in the bag was measured by SIFT-MS at intervals of 1 to 2 hours. The recovery rate according to the storage time was calculated as the ratio to the initial concentration. The recovery rate of each substance according to the storage period (12h, 24h, 36h, 48h) was ACA (66.2%, 62.8%, 55.6%, 52.0%), PPA (77.6%, 72.1%, 63.0%, 58.1%, 86.6%), BTA (86.6%, 81.3%, 71.6%, 66.9%), VLA (94.8%, 89.0%, 76.6%, 71.7%). The recovery rate continued to decrease over the course of 48 hours of storage time. ACA, PPA, and BTA showed the greatest decrease within the initial 12 hours, which is form of exponential decrease. Therefore, we considered a 1~3 degree polynomial regression model and a 1~2 degree exponential decay model. Each developed model was evaluated by r², RMSE, MAPE, AIC, and then a model for each substance was selected. Selected models were tested with recovery rate data from swine farm odor samples. Only the ACA model exhibited a good performance (r² = 0.76).

Several analytical measurement techniques have been developed over the years for ammonia (NH3). However, the field monitoring of NH3 still remains a significant challenge owing to the wide range of possible environmental conditions and NH3 concentration. In this regard, it is imperative to ensure the quality control of techniques to measure the NH3 emission levels reliably. A present study was conducted to compare the five analytical methods for the measurement of atmospheric NH3 via validation tests under laboratory and field conditions. The analytical instruments applied in the present study were based on wet chemistry, gas detection tube, electrochemical sensor, photoacoustic spectroscopy, and cavity ring-down spectroscopy. The reproducibility and linearity of all the analyzed methods were observed to be high with the relative standard deviation and coefficient of determination (R2) being 10% and > 0.9, respectively. In the case of wet chemistry and high NH3 concentration, the measured NH3 results were found to be close to the actual standard gas levels. Response times of electrochemical sensor showed faster from the instruments utilized more than one year and the high NH3 concentrations. In the field tests, NH3 concentration showed higher in the manure storage tank compared with the pig-pen. In both cases, the NH3 concentration levels measured by gas detection tube were found to be quite different from that of wet chemistry. It was proposed that such differences in NH3 concentration could arise due to the inherent instrumental characteristics and the variations in air velocity during sampling/measurement. The periodic instrumental maintenance, verification, replicate analyses, and suitable consideration of environmental factors should be considered for a more reliable measurement of NH3 concentration under real field conditions.

구조와 사육환경이 동일한 3개의 돈방(room A~C)에서 48일 동안 비육돈의 암모니아 농도 및 환기량을 모니터링하여 배출계수를 산정하였다. 실험 결과, 온도 22.5℃, 습도 53.9% 환경에서 평균 암모니아 순발생 농도 5.93 ppm, 환기량 23.7 m3/h·pig로 나타났다. 일별 상관관계 분석결과, 암모니아 농도는 온도와 음의 상관관계(R2: -0.65 ~ -0.53)를 가지는 것으로 나타났으며, 환기량은 암모니아 농도에 거의 영향을 미치지 않는 것으로 나타났다. 암모니아 농도는 이른 오전을 기점으로 서서히 증가 경향을 보이다가 12~13시경 최댓값에 도달하였고, 상호 상관도가 높은 온도, 습도, 환기량의 경우 14~15시에 최댓값을 갖는 것으로 분석되었다. 시간별 데이터 상관관계 분석결과, 암모니아 배출량에 영향을 미치는 요소는 암모니아 농도(R2=0.71)와 환기량(R2=0.61)으로 이 중, 암모니아 농도가 더 상관성이 높은 것으로 분석되었다. 암모니아 배출계수는 2.28 g/d·pig로 분석되었다.