Compartment fire tests were performed using kerosene and Jet A-1 as fire sources to evaluate the relationship between flame temperature and opening size. The tests were performed for a fire caused by the release of kerosene owing to vehicle impact, and for a fire caused by the release of Jet-A-1 owing to airplane collision. The compartment fire tests were performed using a 1/3-scale model of a metal storage cask when the flame temperature was deemed to be the highest. We found the combustion time of Jet-A-1 to be shorter than that of kerosene, and consequently, the flame temperature of Jet-A-1 was measured to be higher than that of kerosene. When the opening was installed on the compartment roof, even though the area of the opening was small, the ventilation factor was large, resulting in a high flame temperature and long combustion. Therefore, the position of the opening is a crucial factor that affects the flame temperature. When the metal storage cask was stored in the compartment, the flame temperature decreased proportionally with the energy that the metal storage cask received from the flame.