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카본블랙 첨가량에 따른 인산형 연료전지(PAFC) 분리판용 천연흑연-고분자복합재료의 전기비저항 KCI 등재 SCOPUS

Electrical Resistivity of Natural Graphite/Polymer Composite based Bipolar Plates for Phosphoric Acid Fuel Cells by Addition of Carbon Black

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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

Conductive polymer composites with high electrical and mechanical properties are in demand for bipolar plates of phosphoric acid fuel cells (PAFC). In this study, composites based on natural graphite/fluorinated ethylene propylene (FEP) and different ratios of carbon black are mixed and hot formed into bars. The overall content of natural graphite is replaced by carbon black (0.2 wt% to 3.0 wt%). It is found that the addition of carbon black reduces electrical resistivity and density. The density of composite materials added with carbon black 3.0 wt% is 2.168 g/cm3, which is 0.017 g/cm3 less than that of non-additive composites. In-plane electrical resistivity is 7.68 μΩm and through-plane electrical resistivity is 27.66 μΩm. Compared with non-additive composites, in-plane electrical resistivity decreases by 95.7 % and through-plane decreases by 95.9 %. Also, the bending strength is about 30 % improved when carbon black is added at 2.0 wt% compared to non-additive cases. The decrease of electrical resistivity of composites is estimated to stem from the carbon black, which is a conductive material located between melted FEP and acts a path for electrons; the increasing mechanical properties are estimated to result from carbon black filling up pores in the composites.

목차
Abstract
1.서 론
2. 실험방법
    2.1 제조 방법
    2.2 원료 분석
    2.3 부피밀도
    2.4 미세구조 분석
    2.5 굽힘 강도 측정 및 평가
    2.6 전기비저항 측정
3. 결과 및 고찰
    3.1 원료 분석
    3.2 부피밀도
    3.3 미세조직 관찰
    3.4 굽힘 강도
    3.5 전기 비저항 분석
4.결 론
References
저자
  • 김효창(금오공과대학교 신소재공학과) | Hyo-Chang Kim (School of Materials Science and Engineering, Kumoh National Institute of Technology)
  • 이상민(금오공과대학교 신소재연구소) | Sang-Min Lee (Advanced Material Research Center, Kumoh National Institute of Technology)
  • 남기법(금오공과대학교 신소재연구소) | Gibeop Nam (Advanced Material Research Center, Kumoh National Institute of Technology)
  • 노재승(금오공과대학교 신소재공학과) | Jae-Seung Roh (School of Materials Science and Engineering, Kumoh National Institute of Technology) Corresponding author