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Effect of Low-Temperature Sintering on Electrical Properties and Aging Behavior of ZVMNBCD Varistor Ceramics KCI 등재 SCOPUS

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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

This paper focuses on the electrical properties and stability against DC accelerated aging stress of ZnO-V2O5-MnO2- Nb2O5-Bi2O3-Co3O4-Dy2O3 (ZVMNBCD) varistor ceramics sintered at 850 - 925 ℃. With the increase of sintering temperature, the average grain size increases from 4.4 to 11.8 mm, and the density of the sintered pellets decreases from 5.53 to 5.40 g/ cm3 due to the volatility of V2O5, which has a low melting point. The breakdown field abruptly decreases from 8016 to 1,715 V/cm with the increase of the sintering temperature. The maximum non-ohmic coefficient (59) is obtained when the sample is sintered at 875 ℃. The samples sintered at below 900 oC exhibit a relatively low leakage current, less than 60 mA/cm2. The apparent dielectric constant increases due to the increase of the average grain size with the increase of the sintering temperature. The change tendency of dissipation factor at 1 kHz according to the sintering temperature coincides with the tendency of the leakage current. In terms of stability, the samples sintered at 900 ℃ exhibit both high non-ohmic coefficient (45) and excellent stability, 0.8% in ΔEB/EB and -0.7% in Δα/α after application of DC accelerated aging stress (0.85 EB/85 oC/24 h).

목차
Abstract
1. Introduction
2. Experimental Procedure
    2.1 Specimen Preparation
    2.2 Microstructure Analysis
    2.3 Electrical and Dielectric Measurement
    2.4 Aging Stress Measurement
3. Results and Discussion
4. Conclusions
References
저자
  • Choon-Woo Nahm(Department of Electrical Engineering, Dongeui University) Corresponding author