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Facile Synthesis and Characterization of Reduced Graphene Oxide–Zinc Ferrite Nanocomposite as Adsorbent in Aqueous Media KCI 등재 SCOPUS

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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

Here, Zn ferrite is synthesized along with reduced graphene oxide (rGO) by a facile one-step hydrothermal method. The difference between the synthesized nanocomposites with those in other reported work is that the reaction conditions in this work are 160 oC for 12 h. The synthesized products are characterized by field-emission scanning electron microscopy, X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and attenuated total reflection. Further, the adsorption property of rGO–Zn ferrite (rGZF) nanocomposite is studied after confirming its successful synthesis. The adsorption capacity of rGZFs toward rhodamine B (RB) is ˃ 9.3 mg/g, whereas that of bare ZF nanoparticles is 1.8 mg/g in aqueous media. The efficiencies of rGZF and bare ZF to remove RB are 99 % and 20 %, respectively. Employing rGZF, 60 % of RB is decomposed within 5 min. The kinetic study reveals that the adsorption process of removing RB by bare Zn ferrite follows pseudo-firstorder kinetics. However, after zinc ferrite is incorporated with rGO, the kinetics changes to pseudo-second-order. Furthermore, the Langmuir isotherm is accomplished by the adsorption process employing rGZF, indicating that a monolayer adsorption process occurs. The thermodynamic parameters of the process are also calculated.

목차
Abstract
1. Introduction
2. Experimental
    2.1 Materials
    2.2 Preparation of GO
    2.3 Preparation of the rGZF nanocomposites
    2.4 Characterization
    2.5 Adsorption technique
3. Results and discussions
4. Conclusions
References
저자
  • Fatima Tuz Johra(Department of Materials Science and Engineering, Kookmin University)
  • Woo-Gwang Jung(Department of Materials Science and Engineering, Kookmin University) Corresponding author