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회전형 원자층 증착기의 회전 속도에 따른 SnSe 분말 상 ZnO 박막 증착 KCI 등재

Rotation Speed Dependence of ZnO Coating Layer on SnSe powders by Rotary Atomic Layer Deposition Reactor

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한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

The SnSe single crystal shows an outstanding figure of merit (ZT) of 2.6 at 973 K; thus, it is considered to be a promising thermoelectric material. However, the mass production of SnSe single crystals is difficult, and their mechanical properties are poor. Alternatively, we can use polycrystalline SnSe powder, which has better mechanical properties. In this study, surface modification by atomic layer deposition (ALD) is chosen to increase the ZT value of SnSe polycrystalline powder. SnSe powder is ground by a ball mill. An ALD coating process using a rotary-type reactor is adopted. ZnO thin films are grown by 100 ALD cycles using diethylzinc and H2O as precursors at 100oC. ALD is performed at rotation speeds of 30, 40, 50, and 60 rpm to examine the effects of rotation speed on the thin film characteristics. The physical and chemical properties of ALD-coated SnSe powders are characterized by scanning and tunneling electron microscopy combined with energy-dispersive spectroscopy. The results reveal that a smooth oxygenrich ZnO layer is grown on SnSe at a rotation speed of 30 rpm. This result can be applied for the uniform coating of a ZnO layer on various powder materials.

목차
Abstract
1. 서 론
2. 실험 방법
3. 결과 및 고찰
4. 결 론
References
저자
  • 정명준(서울과학기술대학교 신소재공학과) | Myeong Jun Jung (Department of Materials Science and Engineering, Seoul National University of Science and Technology)
  • 윤예준(서울과학기술대학교 신소재공학과) | Ye Jun Yun (Department of Materials Science and Engineering, Seoul National University of Science and Technology)
  • 변종민(서울과학기술대학교 신소재공학과/서울과학기술대학교 분말기술연구소) | Jongmin Byun (Department of Materials Science and Engineering, Seoul National University of Science and Technology/The Institute of Powder Technology, Seoul National University of Science and Technology)
  • 최병준(서울과학기술대학교 신소재공학과/서울과학기술대학교 분말기술연구소) | Byung Joon Choi (oul National University of Science and Technology/The Institute of Powder Technology, Seoul National University of Science and Technology) Corresponding Author