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Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8 나노결정질 연자성 합금의 P함량에 따른 미세구조 및 자기적 특성 변화 관찰에 관한 연구 KCI 등재

A Study on the Microstructure and Magnetic Properties of Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8 Nanocrystalline Soft Magnetic Alloys with varying P Content

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한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

We investigate the effect of phosphorous content on the microstructure and magnetic properties of Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8 (x = 1–4 at.%) nanocrystalline soft magnetic alloys. The simultaneous addition of Cu and P to nanocrystalline alloys reportedly decreases the nanocrystalline size significantly, to 10–20 nm. In the P-containing nanocrystalline alloy, P atoms are distributed in an amorphous residual matrix, which suppresses grain growth, increases permeability, and decreases coercivity. In this study, nanocrystalline ribbons with a composition of Fe83.2Si5.33-0.33xB10.67- 0.67xPxCu0.8 (x = 1–4 at.%) are fabricated by rapid quenching melt-spinning and thermal annealing. It is demonstrated that the addition of a small amount of P to the alloy improves the glass-forming ability and increases the resistance to undesirable Fex(B,P) crystallization. Among the alloys investigated in this work, an Fe83.2Si5B10P1Cu0.8 nanocrystalline ribbon annealed at 460oC exhibits excellent soft-magnetic properties including low coercivity, low core loss, and high saturation magnetization. The uniform nanocrystallization of the Fe83.2Si5B10P1Cu0.8 alloy is confirmed by high-resolution transmission electron microscopy analysis.

목차
Abstract
1. 서 론
2. 실험 방법
3. 결과 및 고찰
    3.1 휠 회전 속도(Wheel rotation speed)에 따른Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8(x=0-4 at%) 비정질 리본의 제조 특성
    3.2 Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8(x=0-4at%) 비정질리본의 열적 거동
    3.3 Fe83.2Si5.33-0.33xB10.67-0.67xPxCu0.8(x=0-4at%)의 나노결정화 열처리 및 자기적 특성 분석
4. 결 론
References
저자
  • 임현아(한국재료연구원 분말재료연구본부/부산대학교 재료공학부) | Hyun Ah Im (Metal Powder Department, Korea Institute of Materials Science (KIMS)/Department of Materials Science and Engineering, Pusan National University)
  • 배경훈(한국재료연구원 분말재료연구본부) | Kyoung-Hoon Bae (Metal Powder Department, Korea Institute of Materials Science (KIMS))
  • 남영균(한국재료연구원 분말재료연구본부/부산대학교 재료공학부) | Yeong gyun Nam (Metal Powder Department, Korea Institute of Materials Science (KIMS)/Department of Materials Science and Engineering, Pusan National University)
  • 안수봉(한국재료연구원 분말재료연구본부/부산대학교 재료공학부) | Subong An (Metal Powder Department, Korea Institute of Materials Science (KIMS)/Department of Materials Science and Engineering, Pusan National University)
  • 양상선(한국재료연구원 분말재료연구본부) | Sangsun Yang (Metal Powder Department, Korea Institute of Materials Science (KIMS))
  • 김용진(한국재료연구원 분말재료연구본부) | Yong-Jin Kim (Metal Powder Department, Korea Institute of Materials Science (KIMS))
  • 이정우(부산대학교 재료공학부) | Jung Woo Lee (Department of Materials Science and Engineering, Pusan National University)
  • 정재원(한국재료연구원 분말재료연구본부) | Jae Won Jeong (Metal Powder Department, Korea Institute of Materials Science (KIMS)) Corresponding Author