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WO3/tert-butyl alcohol 슬러리의 동결건조 조건이 다공체의 미세구조 특성에 미치는 영향 KCI 등재

Effect of Freeze Drying Condition of WO3/Tert-Butyl Alcohol Slurry on the Microstructural Characteristics of Porous Body

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한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

The effects of drying temperature on the microstructure of porous W fabricated by the freeze-casting process of tert-butyl alcohol slurry with WO3 powder was investigated. Green bodies were hydrogen-reduced at 800oC for 1 h and sintered at 1000oC for 6 h. X-ray diffraction analysis revealed that WO3 powders were completely converted to W without any reaction phases by hydrogen reduction. The sintered body showed pores aligned in the direction of tertbutyl alcohol growth, and the porosity and pore size decreased as the amount of WO3 increased from 5 to 10v ol%. As the drying temperature of the frozen body increased from -25oC to -10oC, the pore size and thickness of the struts increased. The change in microstructural characteristics based on the amount of powder added and the drying temperature was explained by the growth behavior of the freezing agent and the degree of rearrangement of the solid powder during the solidification of the slurry.

목차
Abstract
1. 서 론
2. 실험방법
3. 실험결과 및 고찰
4. 결 론
References
저자
  • 이의선(서울과학기술대학교 신소재공학과) | Eui Seon Lee (Department of Materials Science and Engineering, Seoul National University of Science and Technology)
  • 허연지(서울과학기술대학교 신소재공학과) | Youn Ji Heo (Department of Materials Science and Engineering, Seoul National University of Science and Technology)
  • 석명진(강원대학교 신소재공학과) | Myung-Jin Suk (Department of Materials Science and Engineering, Kangwon National University)
  • 오승탁(서울과학기술대학교 신소재공학과) | Sung-Tag Oh (Department of Materials Science and Engineering, Seoul National University of Science and Technology) Corresponding Author