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광결정 기반 색 변화 센서의 VOCs 감지능 평가 방법 KCI 등재

Methodology to evaluate the ability of colloidal crystal-based colorimetric sensor to detect VOCs

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실내환경 및 냄새 학회지 (Journal of Odor and Indoor Environment)
한국냄새환경학회 (Korean Society Of Odor Research And Engineering)
초록

As the demand for the monitoring of VOCs increases, various unpowered colorimetric sensors are being developed, but the performance evaluation method of the developed sensors has not been systematically established. In this study, the device, experimental process, and data calculation methods for the performance evaluation of the colorimetric sensors were proposed. An aluminum chamber (70W× 128 L × 40 mm H) was designed to expose the sensor to a constant concentration of VOCs. In addition, an experimental apparatus was devised to evaluate the effect of environmental factors (temperature and humidity) affecting the ability of the sensor to detect VOCs. To calculate the color change value of the sensor corresponding to the concentration of VOCs, the ‘peak wavelength method’ that analyzes the wavelength of the highest intensity for high-concentration VOCs and the ‘spectral centroid method’ using a weighted arithmetic average for low-concentration VOCs were used. As a result of evaluating the ability of the colorimetric sensor to detect VOCs, which was made of polydimethylsiloxane (PMDS) by the method proposed in this study, the wavelength change values (bandgap shift) of the sensor for 1,000 ppm of benzene, toluene, oxylene, and acetone were 0.898 nm, 2.304 nm, 5.775 nm, and 0.249 nm, respectively. The precision was calculated by repeatedly measuring the sensing ability of the sensor 5 times for each type of VOCs. The precision of the sensor responses to benzene, toluene, o-xylene, and acetone were 15.23%, 7.84%, 4.14%, and 30.00% RSD, respectively. The method proposed in this study can be used to evaluate the performance of various types of VOCs colorimetric sensors.

목차
Abstract
1. 서 론
2. 연구내용 및 방법
    2.1 VOCs 가스 제조 및 농도 확인
    2.2 광결정 기반 색 변화 센서
    2.3 센서 감지능 평가용 챔버 설계
    2.4 센서 파장 측정 및 평가 환경
3. 연구 결과
    3.1 재현성과 정밀도 측정을 위한 bandgap shift 분석
    3.2 온도 및 습도 영향
    3.3 센서의 내구성
4. 고 찰
5. 결 론
References
저자
  • 강수경(이화여자대학교 환경공학과) | Soo-Kyung Kang (Department of Environmental Science and Engineering, Ewha Womans University)
  • 장형관(서강대학교 기계공학과) | Hyung-Kwan Chang (Department of Mechanical Engineering, Sogang University)
  • 박정열(서강대학교 기계공학과) | Jungyul Park (Department of Mechanical Engineering, Sogang University)
  • 김정욱(서강대학교 화공생명공학과) | Jungwook Kim (Department of Chemical and Biomolecular Engineering, Sogang University)
  • 조경숙(이화여자대학교 환경공학과) | Kyung-Suk Cho (Department of Environmental Science and Engineering, Ewha Womans University) Corresponding Author