In order for records to be preserved for a long time without physical and chemical transformation, the preservation environment of the library is very important, and environmental problems must be improved through periodic investigation on the preservation environment. Against this background, this study derived fine dust (PM10) and ultrafine dust (PM2.5) concentration data for the libraries, hallways, and workrooms of the National Archives of Korea over two years. There was a difference in the concentration of fine dust and ultrafine dust among facilities, and there was a change in the concentration depending on the month. Both fine dust and ultrafine dust concentrations were present at less than 10 μg/m³ in the libraries. In the hallways, both fine and ultrafine dust concentrations were highest in July. In the workplaces, the monthly fluctuations in the concentration of fine dust and ultrafine dust were large. And the concentration of fine dust and ultrafine dust in the workplaces were higher than those in the library and hallways. Overall, the concentration of fine dust and ultra-fine dust was measured below the maintenance standards stipulated by the Indoor Air Quality Management Act of the Ministry of Environment of Korea in all the investigated facilities. The results of this study are expected to be used as fundamental information to manage the indoor air quality of the facilities of the National Archives.