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비화공식 예광탄 응용을 위한 Dy3+, La3+ 그리고 Ho3+이 도핑된 MgB4O7의 열 발광 특성 분석 KCI 등재 SCOPUS

Determination of Thermoluminescence Properties of MgB4O7 Doped with Dy3+, La3+ and Ho3+ for a Light Tracer Application

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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

Bullets flying with a light from the back are called “tracers”. Tracers are ignited by the combustion gas of the propellant and emit bright light that allows the shooter to visually trace the flight path. Therefore, tracers mark the firing point for allies to assist shooters to hit target quickly and accurately. Conventional tracers are constructed with a mixture of an oxidizing agent, raw metal, and organic fuel. Upon ignition, the inside of the gun can be easily contaminated by the by-products, which can lead to firearm failure during long-term shooting. Moreover, there is a fire risk such as forest fires due to residual flames at impact site. Therefore, it is necessary to develop non-combustion type luminous material; however, this material must still use the heat generated from the propellant, so-called “thermoluminescence (TL)”. This study aims to compare the TL emission of Dy3+, La3+ and Ho3+ doped MgB4O7 phosphors prepared by solid state reaction. The crystal structures of samples were determined by X-ray diffraction and matched with the standard pattern of MgB4O7. Luminescence of various doses (200 ~ 15,000 Gy) of gamma irradiated Dy3+, La3+ and Ho3+ (at different concentrations of 5, 10, 15 and 20 %) doped MgB4O7 were recorded using a luminance/color meter. The intensity of TL yellowish (CIE x = 0.401 ~ 0.486, y = 0.410 ~ 0.488) emission became stronger as the temperature increased and the total gamma-ray dose increased.

목차
Abstract
1. 서 론
2. 실험방법
3. 결과 및 고찰
    3.1. 열 발광체 MgB4O7 구조 및 도핑 확인
    3.2. 열 발광 특성 분석
4.결 론
References
저자
  • 박진우(한국과학기술원) | Jinu Park (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea)
  • 김나경(한국과학기술원) | Nakyung Kim (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea)
  • 최지운(한국과학기술원) | Jiwoon Choi (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea)
  • 고재혁(한국과학기술원) | Jaehyuk Koh (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea)
  • 진희식(풍산기술연구원) | Hee Sik Chin (Poongsan Defense R&D Institute, Gyeongju 38026, Republic of Korea)
  • 정덕형(풍산기술연구원) | Duck Hyeong Jung (Poongsan Defense R&D Institute, Gyeongju 38026, Republic of Korea)
  • 신병하(한국과학기술원) | Byungha Shin (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea) Corresponding author