본 연구는 국내 유통 농산물 535건을 대상으로 잔류농 약 실태조사를 수행하였다. 서울 등 13개 지역에서 수거 한 농산물 시료를 QuEChERS법으로 추출한 후 d-SPE로 정제하여 LC-MS/MS 및 GC-MS/MS로 분석하였다. 농산 물 15품목 535건 중 14품목 288건에서 잔류농약이 검출 (53.8%)되었으며, 검출된 농산물은 사과 40건, 고추 40건, 감귤 33건, 복숭아 31건, 기타 품목 144건이었다. 이 중 잔류허용기준을 초과한 농산물은 배추 1건으로, diniconazole 이 0.18 mg/kg으로 기준치의 약 2배 검출되었다. 총 검출된 농약은 91종으로 살균제 42종, 살충제 48종, 살선충제 1종 이었으며, dinotefuran 91건, carbendazim 75건, tebuconazole 61건, pyraclostrobin 59건이 가장 빈번하게 검출되었다. 따 라서 상기의 결과를 통해 과일류 및 채소류에 대한 지속 적인 잔류실태조사가 필요할 것으로 사료된다.

In this study, we investigated pesticide residue levels in 535 domestically distributed agricultural products in South Korea using multi-residue analysis. Agricultural products from 13 regions, including Seoul, were pretreated using QuEChERS and d-SPE, and subsequently analyzed using LC-MS/MS and GC-MS/MS. Residual pesticides were detected in 288 (53.8%) out of the 535 samples, including 40 of apples, 40 of peppers, 33 of mandarins, 31 of peaches, and 144 other commodities. Furthermore, one sample of Korean cabbage exceeded the permitted maximum residue limit (MRL), diniconazole (0.18 mg/kg), detected at about twice the MRL. In total, 91 types of residual pesticides were detected, including fungicides (42), insecticides (48), and a nematicide. The most frequently detected pesticides were dinotefuran (91), carbendazim (75), tebuconazole (61), and pyraclostrobin (59). Our results showed that continuous monitoring of agricultural products is necessary.

ABSTRACT
Materials and Methods
    시약 및 재료
    표준원액 및 표준용액의 조제
    추출 및 정제
    기기 분석조건
    시험법 유효성 검증
Results and Discussion
    유효성 검증
    품목별 잔류농약 분석 결과
    잔류허용기준 초과
    농약 성분별 검출 결과
Acknowledgement
국문요약
References

• 배지연(식품의약품안전처 식품의약품안전평가원 식품위해평가부 잔류물질과) | Ji-Yeon Bae (Pesticide and Veterinary Drug Residues Division, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety, Cheongju, Korea)
• 윤다영(식품의약품안전처 식품의약품안전평가원 식품위해평가부 잔류물질과) | Da-Young Yun (Pesticide and Veterinary Drug Residues Division, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety, Cheongju, Korea)
• 강남숙(식품의약품안전처 부산지방식품의약품안전청 시험분석센터) | Nam Suk Kang (Center for Food and Drug Analysis, Busan Regional Office of Food and Drug Safety, MFDS, Busan, Korea)
• 최원조(식품의약품안전처 식품의약품안전평가원 식품위해평가부 잔류물질과) | Won Jo Choe (Pesticide and Veterinary Drug Residues Division, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety, Cheongju, Korea) Corresponding author
• 정용현(식품의약품안전처 식품의약품안전평가원 식품위해평가부 잔류물질과) | Yong-Hyeon Jeong (Pesticide and Veterinary Drug Residues Division, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety, Cheongju, Korea)
• 장귀현(식품의약품안전처 식품의약품안전평가원 식품위해평가부 잔류물질과) | Gui Hyun Jang (Pesticide and Veterinary Drug Residues Division, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety, Cheongju, Korea)
• 문귀임(식품의약품안전처 식품의약품안전평가원 식품위해평가부 잔류물질과) | Guiim Moon (Pesticide and Veterinary Drug Residues Division, Food Safety Evaluation Department, National Institute of Food and Drug Safety Evaluation, Ministry of Food and Drug Safety, Cheongju, Korea)