As existing nuclear power plants reach the end of their lifespan, 22 nuclear power plants in korea are scheduled to be permanently shut down and decommissioned by 2050. Chelates are used as decontamination agents during nuclear power plant operation and decommissioning, and as a result, decommissioning waste contains chelates. Chelates contained in radioactive waste are complexed with radionuclides and increases their mobility. So, qualitative and quantitative analysis of chelates contained in radioactive waste is necessary. However, the spectroscopic method (UVVis), previously used for chelate analysis in Korea takes too much time for analysis and cannot analyze two or more chemically similar chelates at the same time. Due to these problems, new methods for analyzing chelate must be developed. Overseas, many cases of chelate analysis using advanced analysis equipment have been reported. CEA in France has developed a chelate analysis method for application to radioactive waste using HPLC-MS (J. Chromatogram. A, 1276, 20-25, 2013). In this method, the existing method of measuring EDTA using a complex of Fe and EDTA was improved to measuring a complex of Ni and EDTA. Based on such overseas cases, we would like to develop an analysis method for chelates in radioactive waste. For this purpose, we will verify similar overseas papers and develop pretreatment methods for mixtures of chelates (EDTA, DTPA, NTA) and metals (Fe, Ni, Cu, etc.) in various media. Finally, we will develop a separation analysis technology for multi-component chelates in nuclear decommissioning waste based on LCMS.

• Seung-Hwan Hyen(Jeju National University (JNU))
• Hee-Jung Im(Jeju National University (JNU)) Corresponding author