In order to prevent accidents via defective ammunition, this paper analyzes recent research on ammunition life prediction methodology. This workanalyzes current shelf-life prediction approaches by comparing the pros and cons of physical modeling, accelerated testing, and statistical analysis-based prediction techniques. Physical modeling-based prediction demonstrates its usefulness in understanding the physical properties and interactions of ammunition. Accelerated testing-based prediction is useful in quickly verifying the reliability and safety of ammunition. Additionally, statistical analysis-based prediction is emphasized for its ability to make decisions based on data. This paper aims to contribute to the early detection of defective ammunition by analyzing ammunition life prediction methodology hereby reducing defective ammunition accidents. In order to prepare not only Korean domestic war situation but also the international affairs from Eastern Europe and Mid East countries, it is very important to enhance the stability of organizations using ammunition and reduce costs of potential accidents.