This study aims to estimate the scope of damage impact with a real-life explosion case and a damage prediction program (ALOHA) and suggest measures to reduce risk by comparing and analyzing the results using a Probit model. After applying it to the ALOHA program, the toxicity, overpressure, and radiant heat damage of 5 tons of storage scopes between 66 to 413 meters, and the real-life case also demonstrated that most of the damage took place within 300 meters of the LPG gas station. In the Probit analysis, the damages due to radiant heat were estimated as first-degree burns (13-50%), while structural damage (0-75%) and glass window breakage (94-100%) were expected from overpressure, depending on the storage volume. After comparing the real-life case and the damage prediction program, this study concluded that the ALOHA program could be used as the scope of damage impacts is nearly the same as the actual case; it also concluded that the analysis using the Probit model could reduce risks by applying calculated results and predicting the probability of human casualties and structural damages.