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겔 전해질로 구성된 전기변색 거울의 내구성 향상 KCI 등재

Improving the Cyclic Stability of Electrochromic Mirrors Composed of Gel Electrolyte

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한국응용과학기술학회지 (The Korean Society of Applied Science and Technology)
한국응용과학기술학회(구 한국유화학회) (The Korean Society of Applied Science and Technology (KSAST))
초록

The reversible metal electrodeposition (RME) process is used to prepare electrochromic mirrors with reflectivetransparent optical states, by depositing metal particles on transparent conductive substrates. These RME based devices can be used in smart windows to regulate indoor temperatures and light levels, serving dual purposes as lighting elements. Commercialization efforts are focused on achieving large-scale production, long-term durability, and a memory effect that maintains coloration without applied voltage. Enhancing durability has received particular attention, leading to the development of electrochromic mirrors that employ gel electrolytes, which are expected to reduce electrolyte leakage and improve mechanical stability compared to traditional liquid electrolyte devices. The gel electrolytes offer the additional advantage of various colors, by controlling the metal particle size and enabling smoother, denser formations. In this study, we investigated improving the durability of RME devices by adding polyvinyl butyral (PVB) to the liquid electrolyte and optimizing the concentration of PVB. Incorporating 10 % PVB resulted in excellent interfacial properties and superior electrochromic stability, with 92.6 % retention after 1,000 cycles.

목차
Abstract
1. 서 론
2. 실험 방법
    2.1. RME 소자 전해질 제조
    2.2. RME 소자 제작
    2.3. 표면구조 및 화학적 특성 분석
    2.4. RME 소자의 성능 평가
3. 결과 및 고찰
4. 결 론
Acknowledgement
References
<저자소개>
저자
  • 이지형(한국기술교육대학교 에너지신소재화학공학부) | Ji-Hyeong Lee (School of Energy, Materials and Chemical Engineering, Korea University of Technology and Education, Cheonan 31253, Republic of Korea)
  • 강광모(한국기술교육대학교 에너지신소재화학공학부, 한국기술교육대학교 미래융합공학전공) | Kwang-Mo Kang (School of Energy, Materials and Chemical Engineering, Korea University of Technology and Education, Cheonan 31253, Republic of Korea, Future Convergence Engineering, Korea University of Technology and Education, Cheonan 31253, Republic of Korea)
  • 이상범(한국기술교육대학교 에너지신소재화학공학부) | Sang Bum Lee (School of Energy, Materials and Chemical Engineering, Korea University of Technology and Education, Cheonan 31253, Republic of Korea)
  • 나윤채(한국기술교육대학교 에너지신소재화학공학부, 한국기술교육대학교 미래융합공학전공) | Yoon-Chae Nah (School of Energy, Materials and Chemical Engineering, Korea University of Technology and Education, Cheonan 31253, Republic of Korea, Future Convergence Engineering, Korea University of Technology and Education, Cheonan 31253, Republic of Korea) Corresponding author