This study aims to model an accident that occurred at building demolition work sites in Gwangju in 2021 by using functional resonance analysis method(FRAM) and to understand a range of factors contributing to the accident based on the concepts and principles of FRAM and Safety-II. The nature of building demolition works needs to be understood from the viewpoint of socio-technical systems. Not only technical factors but also non-technical factors, including human, organizational, and political factors, and their complicated interrelationships should be considered in the modeling and analysis of accidents happening in the works. Because of the inherent complexity of a demolition works, it is unlikely to specify all of the necessary activities to be conducted in the works and their accountable actors. Additionally, unexpected situations are likely to happen and therefore some activity procedures cannot be followed in a prescribed way, which means that workers sometimes should conduct their activities in an improvisional way. Those characteristics of building demolition works indicate that a traditional accident analysis method based on a linear cause-effect relationship would be inadequate, and that more systemic approaches that can deal with the socio-technical complexities and characteristics of demolition works should be used. With this in mind, we applied FRAM to the accident happening in Gwangju in 2021 and attempted to understand the accident based on the concepts and principles of FRAM and Safety-II (e.g. a functional variablity and its propagation to another function). Lastly, we also suggested ways to enhance the safety of building demolition working sites.