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Sun‑powered synthesis: harnessing multiwall carbon nanotube‑EB photocatalytic magic in a unified photocatalytic‑biocatalytic system for solar‑ driven L‑glutamate production from ɑ‑ketoglutarate KCI 등재

Abhishek Mishra, Rajesh K. Yadav, Shaifali Mishra, Rehana Shahin, Satyam Singh, Abhishek Kumar Gupta, Rajat Singhal, Navneet K. Gupta, Jin‑OoK Baeg, Gamal A. El‑Hiti, Krishna Kumar Yadav, Sunita Singh
  • 언어ENG
  • URLhttps://db.koreascholar.com/Article/Detail/444392
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Carbon Letters (Carbon letters)
한국탄소학회 (Korean Carbon Society)
초록

Artificial photosynthesis, which mimics the natural process used by plants, offers a promising strategy for harnessing solar energy to produce valuable fuels. One intriguing approach is the photocatalyst-enzyme attached system, where a photocatalyst captures light energy and transfers it to an enzyme to drive specific chemical reactions. This study describes the synthesis of a novel photocatalyst (MWCNTCEBr) formed by coupling multiwall carbon nanotubes (MWCNTs) with a dye ethidium bromide (EBr) via a condensation reaction. The resulting photocatalyst exhibits excellent charge separation and migration abilities, leading to enhanced photocatalytic activity. Notably, MWCNTCEBr photocatalyst successfully converts α-Ketoglutarate to L-Glutamate (81.9%) and photo-regeneration of NADH (76.20%) under the influence of solar radiation. Therefore, the study demonstrates the development and the application of MWCNTCEBr photocatalyst for impressive NADH regeneration and bio-transformation.

키워드
Artificial photosynthesisMWCNTCEBr photocatalystNADH regenerationL-Glutamate
목차
Sun-powered synthesis: harnessing multiwall carbon nanotube-EB photocatalytic magic in a unified photocatalytic-biocatalytic system for solar- driven L-glutamate production from ɑ-ketoglutarate
    Abstract
    1 Introduction
    2 Experimental sections
        2.1 Methods and materials required
        2.2 Construction of MWCNTBr photocatalyst via coupling of MWNT and EtBr dye
        2.3 Photo-regeneration of 1,4-NADH from NAD+ co-factor
        2.4 Solar energy responsive conversion of ɑ-Ketoglutarate to L-Glutamate
    3 Results and discussion
        3.1 Characterization 
    4 Conclusion
    Acknowledgements 
    References
저자
  • Abhishek Mishra(Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P. 273010, India)
  • Rajesh K. Yadav(Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P. 273010, India)
  • Shaifali Mishra(Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P. 273010, India)
  • Rehana Shahin(Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P. 273010, India)
  • Satyam Singh(Department of Chemistry and Environmental Science, Madan Mohan Malaviya University of Technology, Gorakhpur, U.P. 273010, India)
  • Abhishek Kumar Gupta(Department of Physics, Harcourt Butler Technical University, Kanpur 208002, India)
  • Rajat Singhal(Centre for Sustainable Technologies, Indian Institute of Science, Bangalore Gulmohar Marg, Bengaluru 560012, India)
  • Navneet K. Gupta(Centre for Sustainable Technologies, Indian Institute of Science, Bangalore Gulmohar Marg, Bengaluru 560012, India)
  • Jin‑OoK Baeg(Korea Research Institute of Chemical Technology, 141 Gajeong‑Ro, Yuseong‑Gu, Daejeon, South Korea)
  • Gamal A. El‑Hiti(Department of Optometry, College of Applied, Medical Sciences, King Saud University, 11433 Riyadh, Saudi Arabia)
  • Krishna Kumar Yadav(Faculty of Science and Technology, Madhyanchal Professional University, Ratibad, Bhopal 462044, India, Environmental and Atmospheric Science Research Group, Scientific Research Centre, A1-Ayen University, Nasiriyah, Thi‑Qar 64001, Iraq)
  • Sunita Singh(Department of Biochemistry, Shivaji College, University of Delhi, New Delhi 110027, India)