Permeable blocks are effective in improving urban water circulation and alleviating heat islands and floods. However, they cause environmental problems owing to their dependence on cement and natural aggregates. In this study, a permeable block was developed, and its performance was verified using ferronickel slag (FNS) as a substitute. The block applied with FNS met the KS F 4419 standard, and an average flexural strength of 4 MPa and a permeability coefficient of 0.1 mm/s or more were secured. This study confirmed that natural aggregate collection could be suppressed, resource efficiency could be improved, greenhouse gas reduction could be achieved, and high value-added industrial byproducts could be used.