Effect of Polymethyl Methacrylate Concentration and Ultraviolet Ozone Treatment on Large-Area Graphene Wet Transfer
Graphene, mechanically exfoliated as a single-atom-thick two-dimensional (2D) material, is renowned for its exceptional carrier mobility and mechanical strength, making it a highly promising material for a wide range of applications; however, following the synthesis of large-area, high-quality graphene, quality degradation, such as tearing, frequently occurs during the transfer process. Currently, chemical vapor deposition (CVD) enables reliable synthesis of large-area graphene, and both wet and dry transfer methods are widely employed to transfer graphene onto various substrates. This study focuses on the wet transfer method to improve transfer efficiency by optimizing the interfacial adhesion among graphene, the polymethyl methacrylate (PMMA) support layer, and the target substrate. To enhance the efficiency of the wet transfer process, the PMMA concentration and ultraviolet ozone (UVO) treatment time were systematically optimized. As a result, a transfer yield of up to 97.16 % was achieved under optimized conditions consisting of 6 % PMMA concentration and 15 min of UVO exposure. This research contributes to the development of highly efficient graphene transfer techniques, which are crucial for reducing production costs and processing time in a wide range of advanced applications such as electronics, energy storage, biomedical devices, environmental monitoring, and materials science.