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Sustainable synthesis of porous reaction-formed SiC ceramics through siliconization of waste fabric-derived carbon preforms using reclaimed Si wafers KCI 등재

Dulal Das, Jinha Kim, Heeju Kim, Sungho Lee, Hyeondeok Jeong
  • 언어ENG
  • URLhttps://db.koreascholar.com/Article/Detail/450978
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Carbon Letters (Carbon letters)
한국탄소학회 (Korean Carbon Society)
초록

Although porous SiC ceramics have been applied across various industries, their high cost limits broader and more extensive utilization. In this study, porous reaction-formed SiC ceramics were fabricated using waste fabric and discarded silicon wafer waste as carbon and silicon sources, respectively. Three types of porous carbon preforms with ∼77% porosity were prepared by varying the initial ratios of waste fabric and furfuryl alcohol. The influence of waste fabric content on the microstructure and mechanical properties of the porous carbon preform was systematically investigated. Higher waste fabric content led to the formation of a more uniform, network-like microstructure, free of large, dense carbon residues. This microstructural refinement enhanced the conversion efficiency of carbon to SiC during the infiltration process. The optimal performance was achieved with a preform containing 75 wt% waste fabric, infiltrated with molten silicon at 1500 °C for 1 h. The resulting SiC ceramics exhibited a compressive strength of 51.4 MPa at 59.4% porosity, surpassing that of porous reaction-bonded SiC ceramics. This approach, involving molten Si infiltration into waste-derived, low-cost carbon preforms, offers a cost-effective and environmentally sustainable route for fabricating high-performance porous carbon structures and porous SiC ceramics for diverse industrial applications.

키워드
Porous SiCReaction forming methodMechanical propertiesWaste-derived carbon preform
목차
Sustainable synthesis of porous reaction-formed SiC ceramics through siliconization of waste fabric-derived carbon preforms using reclaimed Si wafers
    Abstract
    1 Introduction
    2 Experimental methods
    3 Results and discussions
        3.1 Properties of carbon preform
        3.2 Porous reaction-formed SiC ceramics
    4 Conclusions
    References
저자
  • Dulal Das(RAMP Convergence Research Center, Korea Institute of Science and Technology, 92 Chudong-ro Bongdong-eup, Wanju-gun, Jeonbuk 55324, Republic of Korea)
  • Jinha Kim(RAMP Convergence Research Center, Korea Institute of Science and Technology, 92 Chudong-ro Bongdong-eup, Wanju-gun, Jeonbuk 55324, Republic of Korea)
  • Heeju Kim(RAMP Convergence Research Center, Korea Institute of Science and Technology, 92 Chudong-ro Bongdong-eup, Wanju-gun, Jeonbuk 55324, Republic of Korea)
  • Hyeondeok Jeong(RAMP Convergence Research Center, Korea Institute of Science and Technology, 92 Chudong-ro Bongdong-eup, Wanju-gun, Jeonbuk 55324, Republic of Korea)
  • Sungho Lee(RAMP Convergence Research Center, Korea Institute of Science and Technology, 92 Chudong-ro Bongdong-eup, Wanju-gun, Jeonbuk 55324, Republic of Korea, epartment of Nano Material Engineering, KIST School, University of Science and Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon 34113, Republic of Korea) Corresponding author