This paper proposes an emotional interaction model between human and robot using an android. An android is a sort of humanoid robot that the outward shape of robot is almost the same as that of human. The android is a robot platform to implement and test emotional expressions and human interaction. In order to behave for the android like human, a structure of internal emotion system is very important. In our research, we propose a novel emotional model of android based on biological hormone and emotion space. Proposed emotion model has an advantage that it can represent emotion change as time by hormone dynamics.