The compound of 2,6-Bis[(9-phenylcarbazolyl)ethenyl]naphthalene (BPCEN-1), 2-[6-1-Cyano-2-(9-phenylcarbazoly)vinylnaphthyl]-3-(9-phenylcarbazolyl)acrylonitrile (BPCEN-2), 2,6-Bis[4-(1-naphthy l)phenylamino styrenyl] naphthalene (BNPASN-1), 2-[6-1-Cyano-2-(naphthylphenylaminophenyl) vinylnaphthyl]-3-(naphthylphenylaminophenyl)acrylonitrile (BNPASN-2) was analyzed electrochemically and spectroscopically and can be obtained by bonding phenylcarbazolyl, naphthylphenylaminophenyl and -CN ligands to 2,7-naphthalene. The electrochemical and spectroscopic study resulted in the P-type (BPCEN-1, BNPASN-1) being changed to N-type (BPCEN-2, BNPASN-2) according to -CN bonding despite having the same structure. The value of band gap(Eg) was revealed to be small as HOMO had shifted higher and LUMO lower. The Eg value for naphthylphenylaminophenyl ligand was reduced because it has a smaller HOMO/LUMO value than that of phenylcarbazolyl from a structural perspective. The electrochemical HOMO/LUMO values for BPCEN-1, BPCEN-2, BNPASN-1, BNPASN-2 were measured to be 5.55eV / 2.83eV, 5.73eV / 3.06eV, 5.48eV / 2.78eV, and 5.53eV / 2.98eV, respectively. By -CN ligand, the UV max, Eg and PL max were shifted to longer wavelength in their spectra and the luminescence band could be also confirmed to be broad in the photoluminescence (PL) spectrum.

이 논문은 미분구적법(DQM)을 이용한 탄성지반 위에 놓인 변단면 압축부재의 자유진동에 관한 연구이다. 문헌고찰을 통하여 채택한 지배미분방정식과 경계조건을 DQM에 적용하여 고유진동수를 산출할 수 있는 수치해석법을 개발하였다. DQM에서 수치적분을 위한 격자점의 선택은 Chebyshev-Gauss-Lobatto 법을 택하고, 고유치의 산정은 QR 알고리듬을 이용하였다. 타문헌과의 결과비교를 통하여 본 연구의 걸과가 타당함을 보였고, DQM에 대한 적용성 검토에서 고유진동수의 산출이 매우 안정적임을 보였다.