Recently carbon fiber reinforced plastic(CFRP) has been used structural materials in corrosive environment such as for water, chemical tank and chemical pipes. However, mechanical properties of such materials may change when CFRP are exposed to corrosive environment for long periods of time. Therefore, it is important to understand the effect of moisture absorption on mechanical properties of the CFRP. In this study, degradation behavior of immersed carbon fiber/epoxy resin composite material was investigated using acoustic emission(AE) technique. Fracture toughness test are performed on the compact tension(CT) test specimens that are pilled by two types of laminates [0˚2/90˚2]3s and [0˚2/90˚2]6sDuring the fracture toughness test, AE test was carried out to monitor the damage of CFRP by moisture absorption. In spite of the change of moisture absorption rate, the fracture toughness of CFRP was not change. As immersion time increased, AE event count numbers decreased in low amplitude range of AE for amplitude distribution histogram. The event in low amplitude range was known to be generated by debonding of matrix-fiber interface. Therefore, decrease of AE event count numbers in low amplitude range represents that debonding of matrix-fiber interface which was probably generated by moisture absorption.