BaMoO4:Tb3+ phosphor powders were synthesized with different concentrations of Tb3+ ions using the solid-state reaction method. XRD patterns showed that all the phosphors, irrespective of the concentration of Tb3+ ions, had tetragonal systems with two main (112) and (004) diffraction peaks. The excitation spectra of the Tb3+-doped BaMoO4 phosphors consisted of an intense broad band centered at 290 nm in the range of 230-330 nm and two weak bands. The former broad band corresponded to the 4f8 →4f75d1 transition of Tb3+ ions; the latter two weak bands were ascribed to the 7F2→ 5D3 (471 nm) and 7F6→ 5D4 (492 nm) transitions of Tb3+. The main emission band, when excited at 290 nm, showed a strong green band at 550 nm arising from the 5D4→ 7F5 transition of Tb3+ ions. As the concentration of Tb3+ increased from 1 to 10 mol%, the intensities of all the emission lines gradually increased, approached maxima at 10 mol% of Tb3+ ions, and then showed a decreasing tendency with further increase in the Tb3+ ions due to the concentration quenching effect. The critical distance between neighboring Tb3+ ions for concentration quenching was calculated and found to be 12.3 Å, which indicates that dipoledipole interaction was the main mechanism for the concentration quenching of the 5D4→ 7F5 transition of Tb3+ in the BaMoO4:Tb3+ phosphors.
Manufacturing firms have adapted seriously the Design for Manufacture and Assembly (DFMA) techniques which consider concurrently all factors related to the product development by using effective communications and sharing of information on product development processes. This study performed modelling and characterizing the data related to product manufacturing information for Design for Manufacture(DFM) evaluation and analysis. It adapted component-based development method for communicating and managing manufacturing information among distributed manufacturing organizations. Introducing component-based development offers safety and speed to network based system. This development using Unified Modelling Language(UML) provides efficient way for reconstruction and distribution of applications. Also, the integration of database and component into the internet environment enables to communicate and manage effectively manufacturing information for DFM evaluation and analysis at any place in the world. Therefore this system can make it more reasonable that evaluating, analyzing, and effective decision making of product design using DFM technique.