Organic carbon (OC) and elemental carbon (EC) in PM2.5 influence regional climate change by scattering and absorbing solar radiation. Recent attention has focused on the long-range transport of OC and EC to high-altitude regions due to their potential role in accelerating spring snowmelt. Although subalpine and alpine areas account for only about 1% of South Korea, these high-elevation zones are highly vulnerable to climate change and provide important insights into how ecosystems may respond and adapt in the future. We collected 29 PM2.5 samples near Nogodan Peak (1,440 m a.s.l.) in Jirisan National Park and 10 samples at Seoul National University (91 m a.s.l.) between March 2022 and April 2024 to quantify OC and EC concentrations. The mean concentrations and standard deviations of OC and EC were 2.0±1.4 and 0.2±0.1 μg m-3 in Jirisan, and 3.6±0.9 and 0.3±0.2 μg m-3 in Seoul, respectively. These concentrations are lower than previously reported values across ~20 sites in South Korea, likely due to the national reduction in PM2.5 during the study period. Given these lower concentrations, the effect of EC on snowmelt might have been small in Jirisan. High OC/EC ratios (Jirisan: 22.1; Seoul: 12.5) may reflect biomass burning or the formation of secondary organic aerosols. As biomass burning is projected to increase under future climate scenarios and may alter the source and composition of carbonaceous aerosols, long-term research is essential to better understand their potential impacts on high-altitude ecosystems.

Carbon is not only an essential element for life but also a key player in climate change. The radiocarbon (14C) analysis using accelerator mass spectrometry (AMS) is a powerful tool not only to understand the carbon cycle but also to track pollutants derived from fossil carbon, which have a distinct radiocarbon isotope ratio (Δ14C). Many studies have reported Δ14C of carbon compounds in streams, rivers, rain, snow, throughfall, fine particulate matter (PM2.5), and wastewater treatment plant effluents in South Korea, which are reviewed in this manuscript. In summary, (1) stream and river carbon in South Korea are largely derived from the chemical weathering of soils and rocks, and organic compounds in plants and soils, strongly influenced by precipitation, wastewater treatment effluents, agricultural land use, soil water, and groundwater. (2) Unprecedentedly high Δ14C of precipitation during winter has been reported, which can directly and indirectly influence stream and river carbon. Although we cannot exclude the possibility of local contamination sources of high Δ14C, the results suggest that stream dissolved organic carbon could be older than previously thought, warranting future studies. (3) The 14C analysis has also been applied to quantify the sources of forest throughfall and PM2.5, providing new insights. The 14C data on a variety of ecosystems will be valuable not only to track the pollutants derived from fossil carbon but also to improve our understanding of climate change and provide solutions.

Although rivers cover only 0.5% of the total land area on the Earth, they are windows that show the integrated effects of watershed biogeochemistry. Studies on the loads and properties of riverine carbon have been conducted because they are directly linked with drinking water quality, and because regional or global net ecosystem production (NEP) can be overestimated, unless riverine carbon loads are subtracted. Globally, ~0.8-1.5 Pg yr-1 and ~0.62-2.1 Pg yr-1 of carbon are transported from terrestrial ecosystems to the ocean via rivers and from inland waters to the atmosphere, respectively. Concentrations, δ13C, and fluorescence spectra of riverine carbon have been investigated in South Korea to understand the spatiotemporal changes in the sources. Precipitation as well as land use/land cover can strongly influence the composition of riverine carbon, thus shifting the ratios among DIC, DOC, and POC, which could affect the concentrations, loads, and the degradability of adsorbed organic and inorganic toxic materials. A variety of analyses including 14C and high resolution mass spectroscopy need to be employed to precisely define the sources and to quantify the degradability of riverine carbon. Long-term data on concentrations of major ions including alkalinity and daily discharge have been used to show direct evidence of ecosystem changes in the US. The current database managed by the Korean government could be improved further by integrating the data collected by individual researchers, and by adding the major components ions including DIC, DOC, and POC into the database.