PURPOSES : This study is conducted to evaluate the development of materials for extinguishing ESS(Energy Storage System) fires in electric vehicles using industrial byproducts. METHODS : Grout containing an appropriate amount of fly ash, silica fume, blast furnace slag powder, and ferronikel slag, which are industrial byproducts, was prepared. The fluidity, stress, and mechanical properties were evaluated in accordance with standard test methods. RESULTS : The fluidity of the materials used for the evolution of ESS fires differed depending on the material of the industrial byproducts. In the case of blast furnace slag, its fluidity is low owing to viscosity even when it content is high, and the use of ferronikelsrag is shown to be suitable for the evolution of ESS fires in fluidity and curing tests. CONCLUSIONS : Fire-extinguishing materials using industrial byproducts require a long curing time but exhibit the fluidity required for ESS fire extinguishment. In particular, the curing and fluidity of Peronikel slag and fly ash are suitable for ESS fire extinguishing.