Considering the characteristics of aldehydes among volatile organic compounds, a combined process was established by linking an absorbent and a photocatalytic reactor. Experiments to find the optimal operating conditions of the combined process showed that as the amount of photocatalyst coating increases, the wavelength of the ultraviolet lamp used becomes shorter, the photodegradation rate becomes faster, and the removal efficiency increases. It was also demonstrated that by controlling the relative humidity during the connection process of the combined process, the re-evaporation phenomenon at the front end (absorption area) of the hybrid process can be improved and the removal efficiency at the back end (photocatalytic reaction area) can be significantly enhanced. This confirmed the need for a combined process that complements the advantages and disadvantages of each process.