This study established a method for the simultaneous quantitative analysis of 84 odorous compounds by determining proton transfer reaction rate constants, fragmented ion patterns, and product ion yield ratios through experiments on 33 target compounds and by incorporating previously reported data. In this research, a protontransfer- reaction time-of-flight mass spectrometer (PTR-ToF-MS), a real-time analytical instrument, was employed to quantitatively analyze odorants in process streams and final outlet gases from two wastewater consignment treatment facilities (Facility A and Facility B). The expected odor intensity (EOI) estimation method was further applied to identify the primary odor contributors. Among the final outlet gases, the top five odorcausing substances in Facility A were n-pentanal, acetaldehyde, methylmercaptan, n-hexanol, and n-butanal, while the top five odor-causing substances in Facility B were n-decanal, n-nonanal, acetaldehyde, n-butanal, and n-propanol. The cumulative odor contribution rates of these top five odorants were 94.7% and 91.9% for Facilities A and B, respectively. Although PTR-ToF-MS has inherent limitations in distinguishing isomers and isobars, their individual quantification was achieved through complementary identification and separation by TD-GC-MS. This study provides a basis for simplifying quality control in odor analysis compared with conventional trace-level odor testing methods and proposes a more scientific and effective approach for addressing odor problems.