Decabromodiphenyl ether (BDE209) is a persistent aromatic compound widely associated with environmental pollutants. Given its persistence and possible bioaccumulation, exploring a feasible technique to eradicate BDE209 efficiently is critical for today’s environmentally sustainable societies. Herein, an advanced nanocomposite is elaborately constructed, in which a large number of titanium dioxide ( TiO2) nanoparticles are anchored uniformly on two-dimensional graphene oxide (GO) nanosheets ( TiO2/GO) via a modified Hummer’s method and subsequent solvothermal treatment to achieve efficient photocatalytic degradation BDE209. The obtained TiO2/ GO photocatalyst has excellent photocatalytic due to the intense coupling between conductive GO nanosheets and TiO2 nanoparticles. Under the optimal photocatalytic degradation test conditions, the degradation efficiency of BDE209 is more than 90%. In addition, this study also provides an efficient route for designing highly active catalytic materials.
An all-perovskite oxide heterostructure composed of SrSnO3/Nb-doped SrTiO3 was fabricated using the pulsed laser deposition method. In-plane and out-of-plane structural characterization of the fabricated films were analyzed by x-ray diffraction with θ-2θ scans and φ scans. X-ray photoelectron spectroscopy measurement was performed to check the film’s composition. The electrical transport characteristic of the heterostructure was determined by applying a pulsed dc bias across the interface. Unusual transport properties of the interface between the SrSnO3 and Nb-doped SrTiO3 were investigated at temperatures from 100 to 300 K. A diodelike rectifying behavior was observed in the temperature-dependent current-voltage (IV) measurements. The forward current showed the typical IV characteristics of p-n junctions or Schottky diodes, and were perfectly fitted using the thermionic emission model. Two regions with different transport mechanism were detected, and the boundary curve was expressed by ln I = -1.28V - 13. Under reverse bias, however, the temperature- dependent IV curves revealed an unusual increase in the reverse-bias current with decreasing temperature, indicating tunneling effects at the interface. The Poole-Frenkel emission was used to explain this electrical transport mechanism under the reverse voltages.
Bi2MoO6 (BMO) via the structure-directing role of CO(NH2)2 is successfully prepared via a facile solvothermal route. The structure, morphology, and photocatalytic performance of the nanoflake BMO are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), fluorescence spectrum analysis (PL), UV-vis spectroscopy (UVvis) and electrochemical test. SEM images show that the size of nanoflake BMO is about 50 ~ 200 nm. PL and electrochemical analysis show that the nanoflake BMO has a lower recombination rate of photogenerated carriers than particle BMO. The photocatalytic degradation of tetracycline hydrochloride (TC) by nanoflake BMO under visible light is investigated. The results show that the nanoflake BMO-3 has the highest degradation efficiency under visible light, and the degradation efficiency reached 75 % within 120 min, attributed to the unique hierarchical structure, efficient carrier separation and sufficient free radicals to generate active center synergies. The photocatalytic reaction mechanism of TC degradation on the nanoflake BMO is proposed.
Grazing restoration succession of the degraded grassland is an important aspect in community ecology. Field experiment was carried out to examine how major species restore in first four years restoration following 11 consecutive grazing under different stocking rates in Inner Mongolian steppe. A. frigida and P. acaulis are the most important two species in the all treatments (NG, LG, MG and HG) after four years restoration, although they had high fluctuation. The biomasses of these two species account for 40-90% of total biomass. Especially in no grazing area, which was exclosured since 1990, A. frigida and P. acaulis are still the most important two species in the community. These results suggested A. frigida and P. acaulis conununity are quite stable, and will keep long-time if no special measurements were taken during the restoration of the degraded grassland.
To explore the relationship of species diversity and aboveground productivity in grazing ecosystem is very important to manage grassland. We used the four years' data to check this relationship and to look how abiotic factor affect species diversity and aboveground productivity. We found a good linear relationship between species diversity and aboveground productivity in all previous grazing sites, while no any relationship was found in the no grazing site. From our results, we concluded that drought affects aboveground productivity more than grazing, while heavy grazing affects species diversity more than drought in Inner Mongolian steppe.
New Jersey Institute of Technology (NJIT), in collaboration with the University of Hawaii (UH), is upgrading Big Bear Solar Observatory (BBSO) by replacing its principal, 65 cm aperture telescope with a modern, off-axis 1.6 m clear aperture instrument from a 1.7 m blank. The new telescope offers a significant incremental improvement in ground-based infrared and high angular resolution capabilities, and enhances our continuing program to understand photospheric magneto-convection and chromospheric dynamics. These are the drivers for what is broadly called space weather - an important problem, which impacts human technologies and life on earth. This New Solar Telescope (NST) will use the existing BBSO pedestal, pier and observatory building, which will be modified to accept the larger open telescope structure. It will be operated together with our 10 inch (for larger field-of-view vector magnetograms, Ca II K and Ha observations) and Singer-Link (full disk Hα, Ca II K and white light) synoptic telescopes. The NST optical and software control design will be similar to the existing SOLARC (UH) and the planned Advanced Technology Solar Telescope (ATST) facility led by the National Solar Observatory (NSO) - all three are off-axis designs. The NST will be available to guest observers and will continue BBSO's open data policy. The polishing of the primary will be done in partnership with the University of Arizona Mirror Lab, where their proof-of-concept for figuring 8 m pieces of 20 m nighttime telescopes will be the NST's primary mirror. We plan for the NST's first light in late 2005. This new telescope will be the largest aperture solar telescope, and the largest aperture off-axis telescope, located in one of the best observing sites. It will enable new, cutting edge science. The scientific results will be extremely important to space weather and global climate change research.