When decommissioning and operating nuclear power plants, a lot of radioactive waste in concentrated waste powder, slurry, sludge, and powder is generated. The radioactive waste, non-conformity for disposal, cannot be treated or disposed of, but is currently being stored instead. To dispose of the waste, the waste can be solidified by mixing with an appropriate solidification agent. However, when the solidification agent and powder particles are mixed as in the conventional method, the final volume of the waste form to be disposed of increases. In order to solve this problem, in this study, volume reduction was achieved, compared to the existing powder, by applying the roll compaction technology to mold the radioactive waste into compressed pellets. Soil, concrete, concentrate waste, and contaminated soil powder were used as test materials, and pellets were prepared under different operating conditions. Subsequently, a compressive strength test was performed to confirm the integrity and optimal process conditions of the manufactured pellets. However, in order to perform the compressive strength test, the upper and lower surfaces of the pellets must be horizontal, but the pellet has the shape of two tetrahedrons joined together. Hence, test specimens for measuring compressive strength were prepared by making a surface treatment jig. The compressive strength test showed a high strength of 5.20~28.20 MPa. The process conditions showing high compressive strengths were selected as the optimal process conditions. Finally, the volume reduction ratios were calculated by measuring the weight, density and volume of the manufactured pellets. The degrees of volume reduction of the manufactured pellets compared to the existing powder were checked. When the roll gap was 0 mm, the average reduction ratios of the test materials were 3.7 for the soil, 4.0 for the concrete, 4.6 for the concentrate waste, and 3.8 for the contaminated soil. When roll gap was 1 mm, the ratios were 2.7 for the soil, 2.9 for the concrete, 3.4 for the concentrate waste, and 2.8 for the contaminated soil. Therefore, from a conservative point of view (Roll gap = 1 mm), when powdered waste is formed into pellets, it means that the volume is reduced by 1/2.7 for soil, 1/2.9 for concrete, 1/3.4 for concentrated waste, and 1/2.8 for contaminated soil.

Radioactive materials emitted from nuclear accident or decommissioning cause soil contamination over wide areas. In the event of such a wide area of contaminated soil, decontamination is inevitable for residents to reside and reuse as industrial land. There are many ways to decontaminate these contaminated soils, but in urgent situations, the soil washing, which has a short process period and relatively high decontamination efficiency, is considered the most suitable. However, the soil washing process of removing fine soil and cesium by using washing liquid as water and adding a flocculating agent (J-AF) generates slurry/sludge-type secondary waste (Cs-contaminated soil + flocculating agent). Since this form of sludge contaminants cannot be disposed, solidification is needed using an appropriate solidification agent to treat wastes for disposal. Therefore, this study devised a treatment method of contaminated fine soils occurring after the soil washing process. This investigation prepared the simulated wastes of contaminated fine soils generated after the soil washing, and pelletized the samples using a roll compactor under the optimum operating conditions. The optimum conditions of the device were determined in the pre-test. Roll speed, feeding rate, and hydraulic pressure were 1.5 rpm, 25 rpm, and 28.44 MPa, respectively. The waste forms were manufactured by incorporating created pellets (H 6.5 × W 9.4 mm) using polymers as solidification agents. Used polymers were main ingredient (YD-128), hardener (G-1034), and diluent (LGE). The optimum mixing ratio was YD-128 : G-1034 = 65 : 35 phr, and LGE was added in an amount of 10wt% of the total mixture. To confirm the disposal suitability of the manufactured waste forms, characterization evaluation was carried out (compressive strength, thermal cycling, immersion, and leaching test). Characterization evaluation revealed a minimum compressive strength of 23.1 MPa, far exceeding 3.44 MPa of the disposal facility waste acceptance criteria. Compressive strength increased to the highest value of 31.90 MPa after immersion test. To examine leaching characteristics, the pH, Electrical Conductivity (EC) and leachability index (􀜮􀯜) of leachates were identified. As results, pH and EC consistently increased or remained constant with leaching time. The average of Co, Cs and Sr nuclides was 17.76, 17.38 and 14.04, respectively, exceeding the value of 6 in the waste acceptance criteria. Effective waste treatment/ disposal can be achieved without increasing volumes of sludge/slurry by enhancing the technique of this research by performing additional studies in the future.