Incorporating nanotechnology into cement composites significantly improves mechanical properties such as strength, toughness, and durability. Graphene, with high tensile strength and large surface area, shows great promise as a nanofiller, but its hydrophobicity complicates its dispersion in cement matrices. This study used a graphene-cellulose nanofiber (G@ CNF) hybrid filler to ensure a highly uniform dispersion within the cement microstructure. The hybrid filler acts as a bridge and efficiently fills voids within the matrix. The planar structure of graphene also provides nucleation sites for hydrated products, leading to a denser microstructure. The cement composite containing 0.01 wt.% graphene exhibited a compressive strength of 72.7 MPa, representing a 47.5% improvement over the plain cement. Furthermore, the resulting cement demonstrated enhanced water resistance compared to graphene oxide-reinforced-cement. This approach offers a cost-effective and sustainable way of producing high-strength, durable cement composite.