To ensure the safety of disposal facilities for radioactive waste, it is essential to quantitatively evaluate the performance of the waste disposal facilities by using safety assessment models. This paper addresses the development of the safety assessment model for the underground silo of Wolseong Low-and Immediate-Level Waste (LILW) disposal facility in Korea. As the simulated result, the nuclides diffused from the waste were kept inside the silo without the leakage of those while the integrity of the concrete is maintained. After the degradation of concrete, radionuclides migrate in the same direction as the groundwater flow by mainly advection mechanism. The release of radionuclides has a positive linear relationship with a half-life in the range of medium half-life. Additionally, the solidified waste form delays and reduces the migration of radionuclides through the interaction between the nuclides and the solidified medium. Herein, the phenomenon of this delay was implemented with the mass transfer coefficient of the flux node at numerical modeling. The solidification effects, which are delaying and reducing the leakage of nuclides, were maintained the integrity of the nuclides. This effect was decreased by increasing the half-life and the mass transfer coefficient of radionuclides.

The organic complexing agents such as ethylenediaminetetraacetic acid (EDTA), nitrilotriacetic acid (NTA), and isosaccharinic acid (ISA) can enhance the radionuclides’ solubility and have the potential to induce the acceleration of radionuclides’ mobility to a far-field from the radioactive waste repository. Hence, it is essential to evaluate the effect of organic complexing agents on radionuclide solubility through experimental analysis under similar conditions to those at the radioactive waste disposal site. In this study, five radionuclides (cesium, cobalt, strontium, iodine, and uranium) and three organic complexing agents (EDTA, NTA, and ISA) were selected as model substances. To simulate environmental conditions, the groundwater was collected near the repository and applied for solubility experiments. The solubility experiments were carried out under various ranges of pHs (7, 9, 11, and 13), temperatures (10°C, 20°C, and 40°C), and concentrations of organic complexing agents (0, 10-5, 10-4, 10-3, and 10-2 M). Experimental results showed that the presence of organic complexing agents significantly increased the solubility of the radionuclides. Cobalt and strontium had high solubility enhancement factors, even at low concentrations of organic complexing agents. We also developed a support vector machine (SVM) model using some of the experimental data and validated it using the rest of the solubility data. The root mean square error (RMSE) in the training and validation sets was 0.012 and 0.016, respectively. The SVM model allowed us to estimate the solubility value under untested conditions (e.g., pH 12, temperature 30°C, ISA 5×10-4 M). Therefore, our experimental solubility data and the SVM model can be used to predict radionuclide solubility and solubility enhancement by organic complexing agents under various conditions.

Radioactive waste containing cellulosic materials such as cotton, paper and wood are being disposed in Low-and intermediate-level radioactive waste disposal site in Gyeongju. Cellulose has recently emerged great issue in terms of disposal site safety as it can be decomposed into an organic complex compound, ISA (isosaccharinic acid), under strong alkali conditions (pH 12.5 or higher) formed by the hydrated cement, to accelerate the mobility of the radionuclides in the disposal facility. However, in Korea, there are insufficient criteria for confirming the suitability for disposal of low-and intermediatelevel radioactive wastes including cellulose, and there is no specific method for evaluating the total amount of waste to confirm the suitability of disposal. Therefore, the method of SKB (Swedish Nuclear and Fuel Management Company), which has established acceptance criteria related to the physicalchemistry safety of cellulose, is analyzed to suggest a method for deriving the amount of cellulosecontaining waste disposal. Cellulose, an organic complexing agent, is an important consideration for safety case at the Swedish low-and intermediate-level radioactive waste disposal site SFR. SKB calculated the amount of cellulose generated by separately labeling cellulose-containing wastes of 1-2BMA, Silo and 1BTF (SKB 2013). BLA, a low-level radioactive waste disposal facility, is not considered due to its low radionuclide inventory (~0.2% of SFR’s total radionuclide inventory, SKB 2013). To calculate the amount of cellulose that can be disposed of, information on the mass and volume of hydrated cement (concrete waste, cement solidification waste, disposal container, grouting, disposal shed), the concentration of ISA absorbed in the hydrated cement, and the concentration of ISA dissolved in the groundwater which were used. In addition, the total disposable amount was calculated using the cellulose degradation rate, composition ratio, and the cellulose containing waste volume.

Cellulose-based wastes can be degraded into short-chain organic acids at the cementitious radioactive waste repository. Isosaccharinic acid (ISA), one of the main degradation products, can form the chelate complex with metals and radionuclides, and these complexes have a potential that can accelerate to move the radionuclides to far-field from the repository. This study characterized the amount of generated ISA from typical cellulosic materials in the repository. Two different degradation experiments were conducted under alkaline conditions (saturated with Ca(OH)2 at pH 12.4): i) cellulosic material mixture under an opened condition (partially aerobic), and ii) cellulosic material under an anaerobic condition in a nitrogen-purged glove box. In the first case, three different types of cellulosic materials–paper, cotton, and wood– were mixed at the same ratio, and the experiments were carried out at three different temperatures (20°C, 40°C, and 60°C). It revealed that both the cellulose degradation rate and generated ISA concentration were high at high reaction temperatures, and various soluble degradation products such as formic acid and lactic acid were generated. The cellulose degradation in this work seems to still stay at a peeling-off process. In the second study, each type of cellulosic material was applied in its own batch experiments, and the amount of generated ISA was in the order of paper > wood > cotton. The above two experiments are supposed to be a long-term study until the generated ISA reaches an equilibrium state.

To obtain confidence in the safety of disposal facilities for radioactive waste, it is essential to quantitatively evaluate the performance of the waste disposal facilities by using safety assessment models. Thus, safety assessment models require uncertainty management as a key part of the confidencebuilding process. In application to the numerical modelling, the global sensitivity analysis is widely employed for dealing with parametric and conceptual uncertainties. In particular, the parametric uncertainty can be effectively reduced by minimizing the uncertainty of critical parameters in the safety assessment model. In this paper, the numerical model of each step disposal facility (Silo, Near surface, and Trench type) at Wolsong Low and Immediate Level Waste (LILW) Disposal Center is designed by using a two-dimensional finite element code (COMSOL Multiphysics). In order to determine the critical parameters for non-adsorbed nuclides such as H-3, C-14, Tc-99, we introduced the variance-based sensitivity analysis methodology of the global sensitivity analysis. In the case of Silo type, the density of waste is highly sensitive to the total leakage quantity of all nuclides. Additionally, the initial nuclide concentration of H-3 was identified as another important parameter of H-3. On the other hands, the mass transport coefficient showed a high contribution in C-14 and Tc-99. In other types of disposal facilities, the leaking properties of H-3 are significantly affected by the amount of infiltration water. However, C-14 and Tc-99 were found to be more sensitive to the density of waste.