A bulk porous composite with plantinum nano-dispersion was synthesized in air atmosphere through the combination of several in situ reactions, including the pyrolysis of . A mixture of (dolomite), , and LiF (0.5 wt%, as an additive) was cold isostatically pressed at 200 MPa and sintered at for 2 h. The porous composite ( : Pt=99 : 1 in volume) had a uniformly open-porous structure (porosity: 56%) with three-dimensional (3-D) network and a narrow pore-size distribution, similarly to the porous composites reported before. Catalytic Properties (viz., NO direct decomposition and NO reduction by ) of the composite were investigated up to . In the absence of oxygen, the NO conversion rate reached ~52% for the direct decomposition and ~100% for the reduction by , respectively. The results suggest the possibility of the porous composite as a multifunctional filter, i.e., simultaneous hot gas-filtering and in one component.