Graphitic nitrogen-doped carbon film/nanoparticle composite, in which the films were wrapped and separated by the nanoparticles, was prepared through a simple co-calcination route. Due to its unique porous structure and improved nitrogen content, the as-prepared electrode material could exhibit high specific capacitances of 317.5 F g− 1 at 0.5 A g− 1 and 200.0 F g− 1 at 20 A g− 1, and stable cycling behavior with no capacitance decline after 10,000 cycles in three-electrode system. When assembled in two-electrode capacitor, its specific capacitance could be well kept at 265.5 F g− 1 at 0.5 A g− 1, and thus the supercapacitor with a high energy density of 9.22 Wh kg− 1 was obtained. The superior energy storage properties of the as-prepared material indicate its promising application as high-performance carbon-based electrode for supercapacitors.