The primary heat transport system consists mainly of the in-core fuel channels connected to the steam generators by a system of feeder pipes and headers. The feeders and headers are made of carbon steel. Feeders run vertically upwards from the fuel channels across the face of the reactor and horizontally over the refueling machine to the headers. Structural materials of the primary systems of nuclear power plants (NPPs) are exposed to high temperature and pressure conditions, so that the materials employed in these plants have to take into accounts a useful design life of at least 30 years. The corrosion products, mainly iron oxides, are generated from the carbon steel corrosion which is the main constituent of the feeder pipes and headers of this circuit. Typical film thickness on CANDU-PHWR surface is 75μm or 30mg/cm2. Deposits on PHWR tends to be much thicker than PWR due to use of carbon steel and also for the source of corrosion products available on the carbon steel surface. Degradation of carbon steel for the feeder pipes transferring the primary system coolant by flow-assisted corrosion in high temperature has been reported in CANDU reactors including Point Lapreau, Gentully-2, Darlington and Bruce NPPs. The formation of Fe3O4 film on a carbon steel surface reduces the dissolution rate of steel substantially. The protectiveness of the Fe3O4 film over the carbon steel is affected by the environmental factors and the operational parameters of the feeder pipes, including the velocity, wall shear stress, solution pH, temperature, concentration of dissolved iron, quality of solution, etc. For effective chemical decontamination of these thick oxides containing radionuclides such as Co-60, it is necessary to understand the corrosion behaviors of feeder pipes and the characteristics of oxide formed on it. In this work, we investigated the growth of oxide films that develop on type SA-107 Gr. B carbon steel in high temperature water and steam environment by scanning electron microscopy (SEM) and glow discharge optical emission spectrometry (GD-OES) for the quantification and the solidstate speciation of metal oxide films. This study was especially focused to set the experimental tests conditions how to increase the oxide thickness up to 50 m by changing the oxidation conditions, such as solution chemistry and thermo-hydraulic conditions both temperature and pressure and so on.