There has been an increased awareness of the need to confirm the chloroform exposure associated with using chlorinated household water. Ten of a 30-minute tub bath were normally taken by two volunteers in a bathroom of an apartment. Chloroform concentrations were measured in bathing water and bathroom air, and exhaled breath of the subjects prior to and after bathing. Bathing using chlorinated tap water resulted in a chloroform exposure and caused a body burden. Based on the difference of chloroform concentrations between breath samples collected prior to and after bathing, the chloroform body burden from a 30-minute bath was estimated to be about 8 to 26 folds higher than that prior to the bath. The mean water and bathroom air chloroform concentrations measured to evaluate the body burden were 9.4 ㎍/ℓ and 14.9 ㎍/㎥, respectively. The chloroform level of the bathroom air was 34 to 130 times higher than that of the living-room air. The relationship between the bathroom air and the corresponding breath chloroform concentrations were significant with p=0.03 and R^2=0.47.
Chloroform present in the swimming water disinfected with sodium hypochlorite is released to the air of swimming pools. The air chloroform concentrations were measured in two swimming pools A and B which applied both sodium hypochlorite and ozone. Their mean concentrations are 28.0 ㎎/㎥ and 33.6 ㎍/㎥ in the swimming pools A and B, respectively. On the other hand, the mean water chloroform concentrations in the swimming pools A and B were 23.9 ㎍/ℓ and 19.5 ㎍/ℓ, respectively. The air chloroform concentrations were lower in the swimming pools A and B than those reported by previous studies abroad employed the swimming pools which applied sodium hypochlorte only for water disinfection. The water chloroform concentrations were also lower in this study than in the previous studies. The relationship between the air and water chloroform concentrations measured in this study was significant with p=0.002 and R^2=O.42. At similar time to the indoor air sampling, outdoor air samples were collected at two sites near each of the swimming pools A and B. The mean outdoor air chloroform concentrations near the swimming pools A and B were 0.41 ㎍/㎥ and 0.16 ㎍/㎥, respectively. The outdoor air chloroform concentrations measured in this study were equal to or lower than those reported by previous studies abroad. The chloroform dose inhaled for a typical one-hour swim was estimated to be 25.9 ㎍ per person, corresponding to a specific 0.37 ㎍/㎏ body weight. for a reference 70 ㎏ male adult, while the inh lation dose of chloroform from the outdoor air was estimated to be 5.6 ㎍ per person per day, corresponding to a specific 0.08 ㎍/㎏/day for the same reference male adult.